Title: Olefin metathesis of a ruthenium carbene complex by electrospray ionization in the gas phase
Authors : Hinderling, Christian
Adlhart, Christian
Chen, Peter
Published in : Angewandte Chemie - International Edition
Volume(Issue) : 37
Issue : 19
Pages : 2685
Pages to: 2689
Publisher / Ed. Institution : Wiley
Publisher / Ed. Institution: Hoboken, New Jersey
Issue Date: 16-Oct-1998
License (according to publishing contract) : Licence according to publishing contract
Type of review: Peer review (Publication)
Language : English
Subjects : Gas-phase chemistry; Mass spectrometry; Metathesis; Carbene complexes
Subject (DDC) : 660: Chemical engineering
Abstract: Surprisingly similar reactions in the gas phase and in solution [Eq. (a)]: The ion 1 obtained by electrospray ionization behaves in the gas phase analogously to the corresponding complex [RuCl2(=CHPh)(PCy3)2] in solution. Measured relative rates for ring-opening metathesis are interpreted under the assumption of an intramolecular π complex, which leads to an estimation of the equilibrium constant for π complexation.  
Departement: Life Sciences und Facility Management
Organisational Unit: Institute of Chemistry and Biotechnology (ICBT)
Publication type: Article in scientific Journal
DOI : 10.1002/(SICI)1521-3773(19981016)37:19<2685::AID-ANIE2685>3.0.CO;2-M
ISSN: 1433-7851
URI: https://digitalcollection.zhaw.ch/handle/11475/2086
Appears in Collections:Publikationen Life Sciences und Facility Management

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