Publication type: | Article in scientific journal |
Type of review: | Peer review (publication) |
Title: | Olefin metathesis of a ruthenium carbene complex by electrospray ionization in the gas phase |
Authors: | Hinderling, Christian Adlhart, Christian Chen, Peter |
DOI: | 10.1002/(SICI)1521-3773(19981016)37:19<2685::AID-ANIE2685>3.0.CO;2-M |
Published in: | Angewandte Chemie: International Edition |
Volume(Issue): | 37 |
Issue: | 19 |
Page(s): | 2685 |
Pages to: | 2689 |
Issue Date: | 16-Oct-1998 |
Publisher / Ed. Institution: | Wiley |
Publisher / Ed. Institution: | Hoboken |
ISSN: | 1433-7851 0570-0833 |
Language: | English |
Subjects: | Gas-phase chemistry; Mass spectrometry; Metathesis; Carbene complexes |
Subject (DDC): | 660: Chemical engineering |
Abstract: | Surprisingly similar reactions in the gas phase and in solution [Eq. (a)]: The ion 1 obtained by electrospray ionization behaves in the gas phase analogously to the corresponding complex [RuCl2(=CHPh)(PCy3)2] in solution. Measured relative rates for ring-opening metathesis are interpreted under the assumption of an intramolecular π complex, which leads to an estimation of the equilibrium constant for π complexation. |
URI: | https://digitalcollection.zhaw.ch/handle/11475/2086 |
Fulltext version: | Published version |
License (according to publishing contract): | Licence according to publishing contract |
Departement: | Life Sciences and Facility Management |
Organisational Unit: | Institute of Chemistry and Biotechnology (ICBT) |
Appears in collections: | Publikationen Life Sciences und Facility Management |
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Hinderling, C., Adlhart, C., & Chen, P. (1998). Olefin metathesis of a ruthenium carbene complex by electrospray ionization in the gas phase. Angewandte Chemie: International Edition, 37(19), 2685–2689. https://doi.org/10.1002/(SICI)1521-3773(19981016)37:19<2685::AID-ANIE2685>3.0.CO;2-M
Hinderling, C., Adlhart, C. and Chen, P. (1998) ‘Olefin metathesis of a ruthenium carbene complex by electrospray ionization in the gas phase’, Angewandte Chemie: International Edition, 37(19), pp. 2685–2689. Available at: https://doi.org/10.1002/(SICI)1521-3773(19981016)37:19<2685::AID-ANIE2685>3.0.CO;2-M.
C. Hinderling, C. Adlhart, and P. Chen, “Olefin metathesis of a ruthenium carbene complex by electrospray ionization in the gas phase,” Angewandte Chemie: International Edition, vol. 37, no. 19, pp. 2685–2689, Oct. 1998, doi: 10.1002/(SICI)1521-3773(19981016)37:19<2685::AID-ANIE2685>3.0.CO;2-M.
HINDERLING, Christian, Christian ADLHART und Peter CHEN, 1998. Olefin metathesis of a ruthenium carbene complex by electrospray ionization in the gas phase. Angewandte Chemie: International Edition. 16 Oktober 1998. Bd. 37, Nr. 19, S. 2685–2689. DOI 10.1002/(SICI)1521-3773(19981016)37:19<2685::AID-ANIE2685>3.0.CO;2-M
Hinderling, Christian, Christian Adlhart, and Peter Chen. 1998. “Olefin Metathesis of a Ruthenium Carbene Complex by Electrospray Ionization in the Gas Phase.” Angewandte Chemie: International Edition 37 (19): 2685–89. https://doi.org/10.1002/(SICI)1521-3773(19981016)37:19<2685::AID-ANIE2685>3.0.CO;2-M.
Hinderling, Christian, et al. “Olefin Metathesis of a Ruthenium Carbene Complex by Electrospray Ionization in the Gas Phase.” Angewandte Chemie: International Edition, vol. 37, no. 19, Oct. 1998, pp. 2685–89, https://doi.org/10.1002/(SICI)1521-3773(19981016)37:19<2685::AID-ANIE2685>3.0.CO;2-M.
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