Title: Alkyne hydrothiolation catalyzed by a dichlorobis(aminophosphine) complex of palladium : selective formation of cis-configured vinyl thioethers
Authors : Gerber, Roman
Frech, Christian M.
Published in : Chemistry - a European journal
Volume(Issue) : 18
Issue : 29
Pages : 8901
Pages to: 8905
Publisher / Ed. Institution : Wiley
Issue Date: 2012
License (according to publishing contract) : Licence according to publishing contract
Type of review: Peer review (Publication)
Language : English
Subject (DDC) : 540: Chemistry
Abstract: Cis all round: Dichlorobis[1-(dicyclohexylphosphanyl)piperidine]palladium, [(P{(NC(5)H(10))(C(6)H(11))(2)})(2)Pd(Cl)(2)], is a highly efficient alkyne hydrothiolation catalyst and the first generally applicable system that selectively generates cis-configured anti-Markovnikov adducts in excellent yields within only a few minutes at 120 °C in the presence of only 0.05 mol % of the catalyst (see scheme).
Departement: Life Sciences and Facility Management
Publication type: Article in scientific Journal
DOI : 10.1002/chem.201200388
ISSN: 0947-6539
URI: https://digitalcollection.zhaw.ch/handle/11475/9649
Appears in Collections:Publikationen Life Sciences und Facility Management

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