Please use this identifier to cite or link to this item:
Title: Towards process intensification : remediation of fouling in continuous microscale synthesis of phosphated TiO2
Authors : Hochstrasser, Martin
Jussen, Daniel
Riedlberger, Peter
Published in : Chemical Engineering & Processing: Process Intensification
Volume(Issue) : 121
Pages : 15
Pages to: 23
Publisher / Ed. Institution : Elsevier
Issue Date: 2017
License (according to publishing contract) : CC BY-NC-ND 4.0: Namensnennung - Nicht kommerziell - Keine Bearbeitungen 4.0 International
Type of review: Peer review (Publication)
Language : English
Subjects : TiO2 nanoparticle synthesis; Fouling remediation; Micromixing and micro reaction; Process intensification
Subject (DDC) : 660: Chemical engineering
Abstract: The use of continuous flow microreactors offers an interesting approach among the process intensification tools available. Fouling in a microreactor during synthesis of industrially relevant nanoparticles was investigated. In order to achieve this, microscale synthesis of phosphated TiO2 nanoparticles from titanium(IV) isopropoxide (TTIP) and titanium(IV) butoxide (TBUT) was employed. A continuous three step process, consisting of hydrolysis of the respective alkoxide, phosphate modification and precipitation was developed. The resulting catalyst was characterized by means of nitrogen adsorption, dynamic light scattering and SEM/EDX. It was observed that TTIP resulted in massive fouling, while a stable process was possible with TBUT. This was related to the nucleation time of the particles. The particle size directly after the critical hydrolysis step was investigated. The particles formed with TTIP as a precursor (3.4 nm) were larger than those obtained from TBUT (2.4 nm). Diffusion based reactant concentration gradients within the multilamellar micromixer were calculated, and the corresponding Damköhler numbers for mixing were estimated to be 2.6∙10−3 for TBUT and 3.5∙10−2 for TTIP respectively. These numbers highlight the influence of incomplete mixing on fouling for TTIP as a precursor. Thus, our work demonstrates the necessity to consider the reaction kinetics during process intensification by miniaturization.
Departement: Life Sciences und Facility Management
Organisational Unit: Institute of Chemistry and Biotechnology (ICBT)
Publication type: Article in scientific Journal
DOI : 10.1016/j.cep.2017.07.024
ISSN: 0255-2701
Appears in Collections:Publikationen Life Sciences und Facility Management

Files in This Item:
File Description SizeFormat 
2018_Hochstrasser_Towards_process_intensification.pdf1.08 MBAdobe PDFThumbnail

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.