Absolute configuration from different multifragmentation pathways in light-induced coulomb explosion imaging

Pitzer, Martin; Kastirke, Gregor; Kunitski, Maksim; Jahnke, Till; Bauer, Tobias; Goihl, Christoph; Trinter, Florian; Schober, Carl; Henrichs, Kevin; Becht, Jasper; Zeller, Stefan; Gassert, Helena; Waitz, Markus; Kuhlins, Andreas; Sann, Hendrik; Sturm, Felix; Wiegandt, Florian; Wallauer, Robert; Schmidt, Lothar Ph. H.; Johnson, Allan S.; Mazenauer, Manuel; Spenger, Benjamin; Marquardt, Sabrina; Marquardt, Sebastian; Schmidt-Böcking, Horst; Stohner, Jürgen; Dörner, Reinhard; Schöffler, Markus; Berger, Robert

doi:10.1002/cphc.201501118

Publication type:	Article in scientific journal
Type of review:	Peer review (publication)
Title:	Absolute configuration from different multifragmentation pathways in light-induced coulomb explosion imaging
Authors:	Pitzer, Martin Kastirke, Gregor Kunitski, Maksim Jahnke, Till Bauer, Tobias Goihl, Christoph Trinter, Florian Schober, Carl Henrichs, Kevin Becht, Jasper Zeller, Stefan Gassert, Helena Waitz, Markus Kuhlins, Andreas Sann, Hendrik Sturm, Felix Wiegandt, Florian Wallauer, Robert Schmidt, Lothar Ph. H. Johnson, Allan S. Mazenauer, Manuel Spenger, Benjamin Marquardt, Sabrina Marquardt, Sebastian Schmidt-Böcking, Horst Stohner, Jürgen Dörner, Reinhard Schöffler, Markus Berger, Robert
DOI:	10.1002/cphc.201501118
Published in:	ChemPhysChem
Volume(Issue):	17
Issue:	16
Page(s):	2465
Pages to:	2472
Issue Date:	2016
Publisher / Ed. Institution:	Wiley
ISSN:	1439-4235 1439-7641
Language:	English
Subjects:	Coulomb explosion imaging; Absolute configuration; Chirality; Cold target recoil ion momentum spectroscopy; Synchrotron radiation
Subject (DDC):	530: Physics
Abstract:	The absolute configuration of individual small molecules in the gas phase can be determined directly by light-induced Coulomb explosion imaging (CEI). Herein, this approach is demonstrated for ionization with a single X-ray photon from a synchrotron light source, leading to enhanced efficiency and faster fragmentation as compared to previous experiments with a femtosecond laser. In addition, it is shown that even incomplete fragmentation pathways of individual molecules from a racemic CHBrClF sample can give access to the absolute configuration in CEI. This leads to a significant increase of the applicability of the method as compared to the previously reported complete break-up into atomic ions and can pave the way for routine stereochemical analysis of larger chiral molecules by light-induced CEI.
URI:	https://digitalcollection.zhaw.ch/handle/11475/6244
Fulltext version:	Published version
License (according to publishing contract):	Licence according to publishing contract
Departement:	Life Sciences and Facility Management
Organisational Unit:	Institute of Chemistry and Biotechnology (ICBT)
Appears in collections:	Publikationen Life Sciences und Facility Management

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Pitzer, M., Kastirke, G., Kunitski, M., Jahnke, T., Bauer, T., Goihl, C., Trinter, F., Schober, C., Henrichs, K., Becht, J., Zeller, S., Gassert, H., Waitz, M., Kuhlins, A., Sann, H., Sturm, F., Wiegandt, F., Wallauer, R., Schmidt, L. Ph. H., et al. (2016). Absolute configuration from different multifragmentation pathways in light-induced coulomb explosion imaging. ChemPhysChem, 17(16), 2465–2472. https://doi.org/10.1002/cphc.201501118

Pitzer, M. et al. (2016) ‘Absolute configuration from different multifragmentation pathways in light-induced coulomb explosion imaging’, ChemPhysChem, 17(16), pp. 2465–2472. Available at: https://doi.org/10.1002/cphc.201501118.

M. Pitzer et al., “Absolute configuration from different multifragmentation pathways in light-induced coulomb explosion imaging,” ChemPhysChem, vol. 17, no. 16, pp. 2465–2472, 2016, doi: 10.1002/cphc.201501118.

PITZER, Martin, Gregor KASTIRKE, Maksim KUNITSKI, Till JAHNKE, Tobias BAUER, Christoph GOIHL, Florian TRINTER, Carl SCHOBER, Kevin HENRICHS, Jasper BECHT, Stefan ZELLER, Helena GASSERT, Markus WAITZ, Andreas KUHLINS, Hendrik SANN, Felix STURM, Florian WIEGANDT, Robert WALLAUER, Lothar Ph. H. SCHMIDT, Allan S. JOHNSON, Manuel MAZENAUER, Benjamin SPENGER, Sabrina MARQUARDT, Sebastian MARQUARDT, Horst SCHMIDT-BÖCKING, Jürgen STOHNER, Reinhard DÖRNER, Markus SCHÖFFLER und Robert BERGER, 2016. Absolute configuration from different multifragmentation pathways in light-induced coulomb explosion imaging. ChemPhysChem. 2016. Bd. 17, Nr. 16, S. 2465–2472. DOI 10.1002/cphc.201501118

Pitzer, Martin, Gregor Kastirke, Maksim Kunitski, Till Jahnke, Tobias Bauer, Christoph Goihl, Florian Trinter, et al. 2016. “Absolute Configuration from Different Multifragmentation Pathways in Light-Induced Coulomb Explosion Imaging.” ChemPhysChem 17 (16): 2465–72. https://doi.org/10.1002/cphc.201501118.

Pitzer, Martin, et al. “Absolute Configuration from Different Multifragmentation Pathways in Light-Induced Coulomb Explosion Imaging.” ChemPhysChem, vol. 17, no. 16, 2016, pp. 2465–72, https://doi.org/10.1002/cphc.201501118.