|Title:||Mechanisms for the dehydrogenation of alkanes on platinum : insights gained from the reactivity of gaseous cluster cations, Pt(n)+, n = 1-21|
|Authors :||Adlhart, Christian|
|Published in :||Chemistry - A European Journal|
|Publisher / Ed. Institution :||Wiley|
|License (according to publishing contract) :||Licence according to publishing contract|
|Type of review:||Peer review (Publication)|
|Subjects :||Cluster compounds; Heterogeneous catalysis; Isotope scrambling; Gas-phase reactions|
|Subject (DDC) :||540: Chemistry|
|Abstract:||Rates for the dihydrogen elimination of methane, ethane, and propane with cationic platinum clusters, Ptn+ (1 ≤ n ≤ 21), were measured under binary collision conditions in a Fourier transform ion cyclotron resonance mass spectrometer (FTICR). The reaction rate for a given cluster, Ptn+, follows the trend k(CH4)|
|Departement:||Life Sciences und Facility Management|
|Organisational Unit:||Institute of Chemistry and Biotechnology (ICBT)|
|Publication type:||Article in scientific Journal|
|Appears in Collections:||Publikationen Life Sciences und Facility Management|
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