Title: Mechanisms for the dehydrogenation of alkanes on platinum : insights gained from the reactivity of gaseous cluster cations, Pt(n)+, n = 1-21
Authors : Adlhart, Christian
Uggerud, Einar
Published in : Chemistry - A European Journal
Volume(Issue) : 13
Issue : 24
Pages : 6883
Pages to: 6890
Publisher / Ed. Institution : Wiley
Issue Date: 17-Aug-2007
License (according to publishing contract) : Licence according to publishing contract
Type of review: Peer review (Publication)
Language : English
Subjects : Cluster compounds; Heterogeneous catalysis; Isotope scrambling; Gas-phase reactions
Subject (DDC) : 540: Chemistry
Abstract: Rates for the dihydrogen elimination of methane, ethane, and propane with cationic platinum clusters, Ptn+ (1 ≤ n ≤ 21), were measured under binary collision conditions in a Fourier transform ion cyclotron resonance mass spectrometer (FTICR). The reaction rate for a given cluster, Ptn+, follows the trend k(CH4)
Departement: Life Sciences und Facility Management
Organisational Unit: Institute of Chemistry and Biotechnology (ICBT)
Publication type: Article in scientific Journal
DOI : 10.1002/chem.200700501
ISSN: 0947-6539
URI: https://digitalcollection.zhaw.ch/handle/11475/2204
Appears in Collections:Publikationen Life Sciences und Facility Management

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