| Publication type: | Article in scientific journal |
| Type of review: | Peer review (publication) |
| Title: | Monolayer adsorption for the subcritical lattice gas and partially miscible binary mixtures |
| Authors: | Hocker, Thomas Aranovich, G. L. Donohue, M. D. |
| DOI: | 10.1006/jcis.1998.5971 |
| Published in: | Journal of Colloid and Interface Science |
| Volume(Issue): | 211 |
| Issue: | 1 |
| Page(s): | 61 |
| Pages to: | 80 |
| Issue Date: | 1-Mar-1999 |
| Publisher / Ed. Institution: | Elsevier |
| ISSN: | 0021-9797 |
| Language: | English |
| Subjects: | Behavior; Adsorption; Phase; Lattice-theory |
| Subject (DDC): | 530: Physics |
| Abstract: | Lattice theories have been used extensively to predict and correlate liquid-liquid equilibria in mixtures. Lattice theories also have been used to predict the behavior of gases adsorbing onto solid surfaces. Here, we use a lattice model based on the ideas of Ono and Kondo to predict the phase behavior in adsorbed monolayers for systems that are below their bulk-phase critical points. For such an analysis, it is important that molecular behavior in the bulk and the adsorbed layer is based on consistent assumptions. Here, this is accomplished by treating the fluid in the bulk as well as in the adsorbed layer as a strictly regular solution. Interesting new adsorption isotherms and phase diagrams are generated that provide useful insights into adsorption of both lattice gases (i.e., "mixtures" of molecules and holes) and dense lattice liquids (i.e., "mixtures" of molecules without holes), illustrating the similarities between adsorption of gases and liquids. |
| URI: | https://digitalcollection.zhaw.ch/handle/11475/1653 |
| Fulltext version: | Published version |
| License (according to publishing contract): | Licence according to publishing contract |
| Departement: | School of Engineering |
| Organisational Unit: | Institute of Computational Physics (ICP) |
| Appears in collections: | Publikationen School of Engineering |
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Hocker, T., Aranovich, G. L., & Donohue, M. D. (1999). Monolayer adsorption for the subcritical lattice gas and partially miscible binary mixtures. Journal of Colloid and Interface Science, 211(1), 61–80. https://doi.org/10.1006/jcis.1998.5971
Hocker, T., Aranovich, G.L. and Donohue, M.D. (1999) ‘Monolayer adsorption for the subcritical lattice gas and partially miscible binary mixtures’, Journal of Colloid and Interface Science, 211(1), pp. 61–80. Available at: https://doi.org/10.1006/jcis.1998.5971.
T. Hocker, G. L. Aranovich, and M. D. Donohue, “Monolayer adsorption for the subcritical lattice gas and partially miscible binary mixtures,” Journal of Colloid and Interface Science, vol. 211, no. 1, pp. 61–80, Mar. 1999, doi: 10.1006/jcis.1998.5971.
HOCKER, Thomas, G. L. ARANOVICH und M. D. DONOHUE, 1999. Monolayer adsorption for the subcritical lattice gas and partially miscible binary mixtures. Journal of Colloid and Interface Science. 1 März 1999. Bd. 211, Nr. 1, S. 61–80. DOI 10.1006/jcis.1998.5971
Hocker, Thomas, G. L. Aranovich, and M. D. Donohue. 1999. “Monolayer Adsorption for the Subcritical Lattice Gas and Partially Miscible Binary Mixtures.” Journal of Colloid and Interface Science 211 (1): 61–80. https://doi.org/10.1006/jcis.1998.5971.
Hocker, Thomas, et al. “Monolayer Adsorption for the Subcritical Lattice Gas and Partially Miscible Binary Mixtures.” Journal of Colloid and Interface Science, vol. 211, no. 1, Mar. 1999, pp. 61–80, https://doi.org/10.1006/jcis.1998.5971.
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