1. ZHAW digitalcollection
  2. Life Sciences und Facility Management
  3. Publikationen
  4. Publikationen Life Sciences und Facility Management
Full metadata record
DC FieldValueLanguage
dc.contributor.authorAbele, Stefan-
dc.contributor.authorHöck, Stefan-
dc.contributor.authorSchmidt, Gunther-
dc.contributor.authorFunel, Jacques-Alexis-
dc.contributor.authorMarti, Roger-
dc.date.accessioned2018-10-19T14:26:00Z-
dc.date.available2018-10-19T14:26:00Z-
dc.date.issued2012-
dc.identifier.issn1083-6160de_CH
dc.identifier.issn1520-586Xde_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/11996-
dc.description.abstractThe transfer of a Diels–Alder reaction of (cyclohexa-1,5-dien-1-yloxy)trimethylsilane with α-acetoxyacrylonitrile and acrylonitrile, respectively, from batch to continuous mode is presented, using standard and widely available laboratory equipment. A standard microwave-based system was used as probe for the transfer to flow reactors. Temperature and residence time have been optimized in small coiled-tube reactors and confirmed with two production runs in a flow reactor. The inherent increase in safety caused by the small volumes at high temperatures and the achieved productivity (approximately 100 g/h using acrylonitrile) are offering advantages over the batch mode which suffers from thermokinetic limitations for scale-up.de_CH
dc.language.isoende_CH
dc.publisherAmerican Chemical Societyde_CH
dc.relation.ispartofOrganic Process Research & Developmentde_CH
dc.rightsLicence according to publishing contractde_CH
dc.subjectDiels-Alder Reactionde_CH
dc.subjectMicroreactorde_CH
dc.subjectFlow Chemistryde_CH
dc.subject.ddc540: Chemiede_CH
dc.titleHigh-temperature Diels–Alder reactions : transfer from batch to continuous modede_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementLife Sciences und Facility Managementde_CH
zhaw.organisationalunitInstitut für Chemie und Biotechnologie (ICBT)de_CH
dc.identifier.doi10.1021/op200320wde_CH
zhaw.funding.euNode_CH
zhaw.issue5de_CH
zhaw.originated.zhawYesde_CH
zhaw.pages.end1120de_CH
zhaw.pages.start1114de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume16de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
Appears in collections:Publikationen Life Sciences und Facility Management

Files in This Item:
There are no files associated with this item.
Show simple item record
Abele, S., Höck, S., Schmidt, G., Funel, J.-A., & Marti, R. (2012). High-temperature Diels–Alder reactions : transfer from batch to continuous mode. Organic Process Research & Development, 16(5), 1114–1120. https://doi.org/10.1021/op200320w
Abele, S. et al. (2012) ‘High-temperature Diels–Alder reactions : transfer from batch to continuous mode’, Organic Process Research & Development, 16(5), pp. 1114–1120. Available at: https://doi.org/10.1021/op200320w.
S. Abele, S. Höck, G. Schmidt, J.-A. Funel, and R. Marti, “High-temperature Diels–Alder reactions : transfer from batch to continuous mode,” Organic Process Research & Development, vol. 16, no. 5, pp. 1114–1120, 2012, doi: 10.1021/op200320w.
ABELE, Stefan, Stefan HÖCK, Gunther SCHMIDT, Jacques-Alexis FUNEL und Roger MARTI, 2012. High-temperature Diels–Alder reactions : transfer from batch to continuous mode. Organic Process Research & Development. 2012. Bd. 16, Nr. 5, S. 1114–1120. DOI 10.1021/op200320w
Abele, Stefan, Stefan Höck, Gunther Schmidt, Jacques-Alexis Funel, and Roger Marti. 2012. “High-Temperature Diels–Alder Reactions : Transfer from Batch to Continuous Mode.” Organic Process Research & Development 16 (5): 1114–20. https://doi.org/10.1021/op200320w.
Abele, Stefan, et al. “High-Temperature Diels–Alder Reactions : Transfer from Batch to Continuous Mode.” Organic Process Research & Development, vol. 16, no. 5, 2012, pp. 1114–20, https://doi.org/10.1021/op200320w.


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.