| Publication type: | Article in scientific journal |
| Type of review: | Peer review (publication) |
| Title: | Collisional probes and possible structure of La2C80 |
| Authors: | Yeretzian, Chahan Hansen, Klavis Alvarez, Marcos M. Min, K. S. Gillan, E. G. Holczer, Károly Kaner, Richard B. Whetten, Robert L. |
| DOI: | 10.1016/0009-2614(92)85978-J |
| Published in: | Chemical Physics Letters |
| Volume(Issue): | 196 |
| Issue: | 3-4 |
| Page(s): | 337 |
| Pages to: | 342 |
| Issue Date: | 14-Aug-1992 |
| Publisher / Ed. Institution: | Elsevier |
| Publisher / Ed. Institution: | Amsterdam |
| ISSN: | 0009-2614 1873-4448 |
| Language: | English |
| Subjects: | Surface collisions; Fullerenes; Endohedral fullerene |
| Subject (DDC): | 540: Chemistry |
| Abstract: | The soluble molecule La2C80 recently reported by Alvarez et al. exhibits a robustness similar to other fullerenes. It survives intact for ≃10-6s following impact against solid surfaces Si (100) at up to 200 eV, yielding an estimate Ef>4 eV for fragmentation processes. The high threshold for electron emission suggests that the electron affinity in La2C80- is significantly larger than in C60. These facts seem to rule out an external site for either La atom and disfavor a network-site interpretation, and thus favor endohedral (encapsulation) sites. Among the possible cages, the Ih-C80 fullerene appears to be highly favourable for the oxidation state (La3+)2C6-80. |
| URI: | https://digitalcollection.zhaw.ch/handle/11475/5415 |
| Fulltext version: | Published version |
| License (according to publishing contract): | Licence according to publishing contract |
| Departement: | Life Sciences and Facility Management |
| Organisational Unit: | Institute of Chemistry and Biotechnology (ICBT) |
| Appears in collections: | Publikationen Life Sciences und Facility Management |
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Yeretzian, C., Hansen, K., Alvarez, M. M., Min, K. S., Gillan, E. G., Holczer, K., Kaner, R. B., & Whetten, R. L. (1992). Collisional probes and possible structure of La2C80. Chemical Physics Letters, 196(3-4), 337–342. https://doi.org/10.1016/0009-2614(92)85978-J
Yeretzian, C. et al. (1992) ‘Collisional probes and possible structure of La2C80’, Chemical Physics Letters, 196(3-4), pp. 337–342. Available at: https://doi.org/10.1016/0009-2614(92)85978-J.
C. Yeretzian et al., “Collisional probes and possible structure of La2C80,” Chemical Physics Letters, vol. 196, no. 3-4, pp. 337–342, Aug. 1992, doi: 10.1016/0009-2614(92)85978-J.
YERETZIAN, Chahan, Klavis HANSEN, Marcos M. ALVAREZ, K. S. MIN, E. G. GILLAN, Károly HOLCZER, Richard B. KANER und Robert L. WHETTEN, 1992. Collisional probes and possible structure of La2C80. Chemical Physics Letters. 14 August 1992. Bd. 196, Nr. 3-4, S. 337–342. DOI 10.1016/0009-2614(92)85978-J
Yeretzian, Chahan, Klavis Hansen, Marcos M. Alvarez, K. S. Min, E. G. Gillan, Károly Holczer, Richard B. Kaner, and Robert L. Whetten. 1992. “Collisional Probes and Possible Structure of La2C80.” Chemical Physics Letters 196 (3-4): 337–42. https://doi.org/10.1016/0009-2614(92)85978-J.
Yeretzian, Chahan, et al. “Collisional Probes and Possible Structure of La2C80.” Chemical Physics Letters, vol. 196, no. 3-4, Aug. 1992, pp. 337–42, https://doi.org/10.1016/0009-2614(92)85978-J.
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