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dc.contributor.authorSchinkel, Lena-
dc.contributor.authorLehner, Sandro-
dc.contributor.authorHeeb, Norbert V.-
dc.contributor.authorMarchand, Philippe-
dc.contributor.authorCariou, Ronan-
dc.contributor.authorMcNeill, Kristopher-
dc.contributor.authorBogdal, Christian-
dc.date.accessioned2023-07-28T13:24:00Z-
dc.date.available2023-07-28T13:24:00Z-
dc.date.issued2018-07-07-
dc.identifier.issn0165-9936de_CH
dc.identifier.issn0703-7147de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/28361-
dc.description.abstractChlorinated paraffins (CPs) are high production volume chemicals. Their analysis is demanding and becomes even more challenging in presence of CP transformation products. Chlorinated olefins (COs) are expected thermal CP transformation products that are present in technical CP products and in the environment. Thus, a specific analysis of CPs and COs is important. Commonly, CPs are analysed by gas chromatography electron capture negative ionisation mass spectrometry (GC-ECNI-MS). It was shown that GC-ECNI-MS suffers from in-source formation of COs. Further, selected ion monitoring can lead to false quantification of COs as CPs. Alternative methods based on liquid chromatography and soft ionisation techniques can solve the CP/CO problem. Non-interfered CP data is inevitable for CP transformation studies and non-biased degradation kinetics. Data about CP transformation is urgently needed, but respective studies are challenging. In here, we provided an analytical guide to deal with severe mass interferences of CPs and their transformation products.de_CH
dc.language.isoende_CH
dc.publisherElsevierde_CH
dc.relation.ispartofTrends in Analytical Chemistryde_CH
dc.rightsLicence according to publishing contractde_CH
dc.subjectChlorinated paraffinsde_CH
dc.subjectChlorinated olefinsde_CH
dc.subjectDegradationde_CH
dc.subjectIn-source fragmentationde_CH
dc.subjectSoft ionisationde_CH
dc.subjectMass interferencesde_CH
dc.subjectPersistent organic pollutantsde_CH
dc.subjectTransformationde_CH
dc.subject.ddc660: Technische Chemiede_CH
dc.titleDealing with strong mass interferences of chlorinated paraffins and their transformation products : an analytical guidede_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementLife Sciences und Facility Managementde_CH
zhaw.organisationalunitInstitut für Chemie und Biotechnologie (ICBT)de_CH
dc.identifier.doi10.1016/j.trac.2018.07.002de_CH
zhaw.funding.euNode_CH
zhaw.originated.zhawYesde_CH
zhaw.pages.end124de_CH
zhaw.pages.start116de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume106de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
zhaw.author.additionalNode_CH
zhaw.display.portraitYesde_CH
Appears in collections:Publikationen Life Sciences und Facility Management

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Schinkel, L., Lehner, S., Heeb, N. V., Marchand, P., Cariou, R., McNeill, K., & Bogdal, C. (2018). Dealing with strong mass interferences of chlorinated paraffins and their transformation products : an analytical guide. Trends in Analytical Chemistry, 106, 116–124. https://doi.org/10.1016/j.trac.2018.07.002
Schinkel, L. et al. (2018) ‘Dealing with strong mass interferences of chlorinated paraffins and their transformation products : an analytical guide’, Trends in Analytical Chemistry, 106, pp. 116–124. Available at: https://doi.org/10.1016/j.trac.2018.07.002.
L. Schinkel et al., “Dealing with strong mass interferences of chlorinated paraffins and their transformation products : an analytical guide,” Trends in Analytical Chemistry, vol. 106, pp. 116–124, Jul. 2018, doi: 10.1016/j.trac.2018.07.002.
SCHINKEL, Lena, Sandro LEHNER, Norbert V. HEEB, Philippe MARCHAND, Ronan CARIOU, Kristopher MCNEILL und Christian BOGDAL, 2018. Dealing with strong mass interferences of chlorinated paraffins and their transformation products : an analytical guide. Trends in Analytical Chemistry. 7 Juli 2018. Bd. 106, S. 116–124. DOI 10.1016/j.trac.2018.07.002
Schinkel, Lena, Sandro Lehner, Norbert V. Heeb, Philippe Marchand, Ronan Cariou, Kristopher McNeill, and Christian Bogdal. 2018. “Dealing with Strong Mass Interferences of Chlorinated Paraffins and Their Transformation Products : An Analytical Guide.” Trends in Analytical Chemistry 106 (July): 116–24. https://doi.org/10.1016/j.trac.2018.07.002.
Schinkel, Lena, et al. “Dealing with Strong Mass Interferences of Chlorinated Paraffins and Their Transformation Products : An Analytical Guide.” Trends in Analytical Chemistry, vol. 106, July 2018, pp. 116–24, https://doi.org/10.1016/j.trac.2018.07.002.


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