Please use this identifier to cite or link to this item: https://doi.org/10.21256/zhaw-26491
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dc.contributor.authorKang, Chengjun-
dc.contributor.authorHonciuc, Andrei-
dc.date.accessioned2022-12-20T14:17:38Z-
dc.date.available2022-12-20T14:17:38Z-
dc.date.issued2019-
dc.identifier.issn0009-4293de_CH
dc.identifier.issn2673-2424de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/26491-
dc.description.abstractThe fabrication of colloids has witnessed significant progress during the last decade, however, fabrication of anisotropic colloidal particles with complex geometries still represents a challenging task. Here, we present nano-/micro-sized colloidal architectures which 'grow' directly from nanoparticle seeds by controlled radical polymerization, resembling the growth of plants from seeds in the natural world. Specifically, we use the atom transfer radical polymerization (ATRP) technique to grow colloidal architectures from snowman-shaped Janus nanoparticle seeds (JNPS). The key to this synthetic approach is the asymmetric placement of the ATRP initiators in the bulk of one JNPS lobe. By starting the polymerization, monomers continuously add to the initiator containing the JNPS lobe, which subsequently grows into a larger colloidal structure. By controlling growth conditions mainly through the interaction strength between the monomer and JNPS, a variety of colloidal architectures result, for example, dish-, basket, cocoon-, flower-, helmet- mushroom-, dumpling and pumpkin-like geometries. Furthermore, each of these grown architectures have different surface morphologies, including smooth-, island- and grouped island nanostructures. The present work provides an alternative method to the synthesis of anisotropic particles with complex geometries and tunable surface morphologies, thus enriching the toolbox for the colloid synthesis.de_CH
dc.language.isoende_CH
dc.publisherSchweizerische Chemische Gesellschaftde_CH
dc.relation.ispartofChimiade_CH
dc.rightshttp://creativecommons.org/licenses/by-nc/4.0/de_CH
dc.subjectAnisotropic colloidde_CH
dc.subjectAtom transfer radical polymerization (ATRP)de_CH
dc.subjectJanus nanoparticlede_CH
dc.subjectSurface nanostructurede_CH
dc.subject.ddc540: Chemiede_CH
dc.titleA diversity of asymmetric nano-/microcolloidal architectures grown by ATRP from Janus seedsde_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementLife Sciences und Facility Managementde_CH
zhaw.organisationalunitInstitut für Chemie und Biotechnologie (ICBT)de_CH
dc.identifier.doi10.2533/chimia.2019.324de_CH
dc.identifier.doi10.21256/zhaw-26491-
dc.identifier.pmid30975265de_CH
zhaw.funding.euNode_CH
zhaw.issue4de_CH
zhaw.originated.zhawYesde_CH
zhaw.pages.end328de_CH
zhaw.pages.start324de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume73de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
zhaw.author.additionalNode_CH
zhaw.display.portraitYesde_CH
Appears in collections:Publikationen Life Sciences und Facility Management

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Kang, C., & Honciuc, A. (2019). A diversity of asymmetric nano-/microcolloidal architectures grown by ATRP from Janus seeds. Chimia, 73(4), 324–328. https://doi.org/10.2533/chimia.2019.324
Kang, C. and Honciuc, A. (2019) ‘A diversity of asymmetric nano-/microcolloidal architectures grown by ATRP from Janus seeds’, Chimia, 73(4), pp. 324–328. Available at: https://doi.org/10.2533/chimia.2019.324.
C. Kang and A. Honciuc, “A diversity of asymmetric nano-/microcolloidal architectures grown by ATRP from Janus seeds,” Chimia, vol. 73, no. 4, pp. 324–328, 2019, doi: 10.2533/chimia.2019.324.
KANG, Chengjun und Andrei HONCIUC, 2019. A diversity of asymmetric nano-/microcolloidal architectures grown by ATRP from Janus seeds. Chimia. 2019. Bd. 73, Nr. 4, S. 324–328. DOI 10.2533/chimia.2019.324
Kang, Chengjun, and Andrei Honciuc. 2019. “A Diversity of Asymmetric Nano-/Microcolloidal Architectures Grown by ATRP from Janus Seeds.” Chimia 73 (4): 324–28. https://doi.org/10.2533/chimia.2019.324.
Kang, Chengjun, and Andrei Honciuc. “A Diversity of Asymmetric Nano-/Microcolloidal Architectures Grown by ATRP from Janus Seeds.” Chimia, vol. 73, no. 4, 2019, pp. 324–28, https://doi.org/10.2533/chimia.2019.324.


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