Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Lai, Yu-Ying | - |
| dc.contributor.author | Bornand, Marc | - |
| dc.contributor.author | Chen, Peter | - |
| dc.date.accessioned | 2018-11-13T15:44:32Z | - |
| dc.date.available | 2018-11-13T15:44:32Z | - |
| dc.date.issued | 2012 | - |
| dc.identifier.issn | 0276-7333 | de_CH |
| dc.identifier.issn | 1520-6041 | de_CH |
| dc.identifier.uri | https://digitalcollection.zhaw.ch/handle/11475/12762 | - |
| dc.description.abstract | A series of rhenium trioxo complexes (L-ReO3) was synthesized, characterized, and demonstrated to be active in olefin metathesis. The relationship between perrhenate (ReO4-), perrhenyl (ReO3+), and metathesis-active rhenium complexes (L-ReO3) was elucidated. Their chemical behavior can be tuned through the Lewis acid–base interaction. DFT calculations were performed for the metathesis reaction of L-ReO3 with norbornene, which demonstrates that electron-withdrawing substituents or ligands are beneficial for olefin metathesis activity. Moreover, a rhenium-alkylidene complex was synthesized, which can be activated by B(C6F5)3 to afford an active metathesis catalyst. This system can be regarded as a homogeneous model of the hypothetical species present in the heterogeneous catalytic systems. The findings from the present study are consistent with our previous gas-phase studies and constitute the elucidation of the working principles for the metathesis-active rhenium species on the surface. | de_CH |
| dc.language.iso | en | de_CH |
| dc.publisher | American Chemical Society | de_CH |
| dc.relation.ispartof | Organometallics | de_CH |
| dc.rights | Licence according to publishing contract | de_CH |
| dc.subject.ddc | 540: Chemie | de_CH |
| dc.title | Homogeneous model complexes for supported rhenia metathesis catalysts | de_CH |
| dc.type | Beitrag in wissenschaftlicher Zeitschrift | de_CH |
| dcterms.type | Text | de_CH |
| zhaw.departement | Life Sciences und Facility Management | de_CH |
| zhaw.organisationalunit | Institut für Chemie und Biotechnologie (ICBT) | de_CH |
| dc.identifier.doi | 10.1021/om300852s | de_CH |
| zhaw.funding.eu | No | de_CH |
| zhaw.issue | 21 | de_CH |
| zhaw.originated.zhaw | Yes | de_CH |
| zhaw.pages.end | 7565 | de_CH |
| zhaw.pages.start | 7558 | de_CH |
| zhaw.publication.status | publishedVersion | de_CH |
| zhaw.volume | 31 | de_CH |
| zhaw.publication.review | Peer review (Publikation) | de_CH |
| Appears in collections: | Publikationen Life Sciences und Facility Management | |
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Lai, Y.-Y., Bornand, M., & Chen, P. (2012). Homogeneous model complexes for supported rhenia metathesis catalysts. Organometallics, 31(21), 7558–7565. https://doi.org/10.1021/om300852s
Lai, Y.-Y., Bornand, M. and Chen, P. (2012) ‘Homogeneous model complexes for supported rhenia metathesis catalysts’, Organometallics, 31(21), pp. 7558–7565. Available at: https://doi.org/10.1021/om300852s.
Y.-Y. Lai, M. Bornand, and P. Chen, “Homogeneous model complexes for supported rhenia metathesis catalysts,” Organometallics, vol. 31, no. 21, pp. 7558–7565, 2012, doi: 10.1021/om300852s.
LAI, Yu-Ying, Marc BORNAND und Peter CHEN, 2012. Homogeneous model complexes for supported rhenia metathesis catalysts. Organometallics. 2012. Bd. 31, Nr. 21, S. 7558–7565. DOI 10.1021/om300852s
Lai, Yu-Ying, Marc Bornand, and Peter Chen. 2012. “Homogeneous Model Complexes for Supported Rhenia Metathesis Catalysts.” Organometallics 31 (21): 7558–65. https://doi.org/10.1021/om300852s.
Lai, Yu-Ying, et al. “Homogeneous Model Complexes for Supported Rhenia Metathesis Catalysts.” Organometallics, vol. 31, no. 21, 2012, pp. 7558–65, https://doi.org/10.1021/om300852s.
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