Full metadata record
DC FieldValueLanguage
dc.contributor.authorLee, Seung-Heon-
dc.contributor.authorYoo, Ba-Wool-
dc.contributor.authorYun, Hoseop-
dc.contributor.authorJazbinsek, Mojca-
dc.contributor.authorKwon, O-Pil-
dc.date.accessioned2018-09-18T14:21:58Z-
dc.date.available2018-09-18T14:21:58Z-
dc.date.issued2015-
dc.identifier.issn0022-2860de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/10790-
dc.description.abstractA new organic π-conjugated quinolinium derivative was designed and synthesized in order to investigate the influence of the anion structure on characteristics of the crystal. The quinolinium derivative consists of a 2-(4-hydroxy-3-methoxystyryl)-1-methylquinolinium (HMQ) cation and a 4-vinylbenzenesulfonate (VBS) counter anion, which contains an electron-rich vinyl group. Single HMQ-VBS crystals, grown by a solution growth method in methanol, exhibited a monoclinic P21/c space group symmetry. Compared to the previously reported HMQ analogous crystal (HMQ-T), which bears a 4-methylbenzenesulfonate counter anion, the HMQ-VBS crystals generally have similar features of molecular alignment, but show different characteristics of hydrogen bonds related to the anion-anion and anion-cation interactions, as well as π-π stacking associated with the cation-cation interactions. Consequently, HMQ-VBS exhibits significantly different physical properties, including linear absorption and fluorescence in the crystalline state, even though these properties are identical to HMQ-T's in the solution state.de_CH
dc.language.isoende_CH
dc.publisherElsevierde_CH
dc.relation.ispartofJournal of Molecular Structurede_CH
dc.rightsLicence according to publishing contractde_CH
dc.subjectQuinoliniumde_CH
dc.subjectπ-conjugated compoundde_CH
dc.subjectOrganic crystalsde_CH
dc.subjectSupramolecular interactionsde_CH
dc.subject.ddc540: Chemiede_CH
dc.titleOrganic styryl quinolinium crystal with aromatic anion bearing electron-rich vinyl groupde_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementSchool of Engineeringde_CH
zhaw.organisationalunitInstitute of Computational Physics (ICP)de_CH
dc.identifier.doi10.1016/j.molstruc.2015.07.071de_CH
zhaw.funding.euNode_CH
zhaw.originated.zhawYesde_CH
zhaw.pages.end365de_CH
zhaw.pages.start359de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume1100de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
Appears in collections:Publikationen School of Engineering

Files in This Item:
There are no files associated with this item.
Show simple item record
Lee, S.-H., Yoo, B.-W., Yun, H., Jazbinsek, M., & Kwon, O.-P. (2015). Organic styryl quinolinium crystal with aromatic anion bearing electron-rich vinyl group. Journal of Molecular Structure, 1100, 359–365. https://doi.org/10.1016/j.molstruc.2015.07.071
Lee, S.-H. et al. (2015) ‘Organic styryl quinolinium crystal with aromatic anion bearing electron-rich vinyl group’, Journal of Molecular Structure, 1100, pp. 359–365. Available at: https://doi.org/10.1016/j.molstruc.2015.07.071.
S.-H. Lee, B.-W. Yoo, H. Yun, M. Jazbinsek, and O.-P. Kwon, “Organic styryl quinolinium crystal with aromatic anion bearing electron-rich vinyl group,” Journal of Molecular Structure, vol. 1100, pp. 359–365, 2015, doi: 10.1016/j.molstruc.2015.07.071.
LEE, Seung-Heon, Ba-Wool YOO, Hoseop YUN, Mojca JAZBINSEK und O-Pil KWON, 2015. Organic styryl quinolinium crystal with aromatic anion bearing electron-rich vinyl group. Journal of Molecular Structure. 2015. Bd. 1100, S. 359–365. DOI 10.1016/j.molstruc.2015.07.071
Lee, Seung-Heon, Ba-Wool Yoo, Hoseop Yun, Mojca Jazbinsek, and O-Pil Kwon. 2015. “Organic Styryl Quinolinium Crystal with Aromatic Anion Bearing Electron-Rich Vinyl Group.” Journal of Molecular Structure 1100: 359–65. https://doi.org/10.1016/j.molstruc.2015.07.071.
Lee, Seung-Heon, et al. “Organic Styryl Quinolinium Crystal with Aromatic Anion Bearing Electron-Rich Vinyl Group.” Journal of Molecular Structure, vol. 1100, 2015, pp. 359–65, https://doi.org/10.1016/j.molstruc.2015.07.071.


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.