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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Seung-Heon | - |
dc.contributor.author | Yoo, Ba-Wool | - |
dc.contributor.author | Yun, Hoseop | - |
dc.contributor.author | Jazbinsek, Mojca | - |
dc.contributor.author | Kwon, O-Pil | - |
dc.date.accessioned | 2018-09-18T14:21:58Z | - |
dc.date.available | 2018-09-18T14:21:58Z | - |
dc.date.issued | 2015 | - |
dc.identifier.issn | 0022-2860 | de_CH |
dc.identifier.uri | https://digitalcollection.zhaw.ch/handle/11475/10790 | - |
dc.description.abstract | A new organic π-conjugated quinolinium derivative was designed and synthesized in order to investigate the influence of the anion structure on characteristics of the crystal. The quinolinium derivative consists of a 2-(4-hydroxy-3-methoxystyryl)-1-methylquinolinium (HMQ) cation and a 4-vinylbenzenesulfonate (VBS) counter anion, which contains an electron-rich vinyl group. Single HMQ-VBS crystals, grown by a solution growth method in methanol, exhibited a monoclinic P21/c space group symmetry. Compared to the previously reported HMQ analogous crystal (HMQ-T), which bears a 4-methylbenzenesulfonate counter anion, the HMQ-VBS crystals generally have similar features of molecular alignment, but show different characteristics of hydrogen bonds related to the anion-anion and anion-cation interactions, as well as π-π stacking associated with the cation-cation interactions. Consequently, HMQ-VBS exhibits significantly different physical properties, including linear absorption and fluorescence in the crystalline state, even though these properties are identical to HMQ-T's in the solution state. | de_CH |
dc.language.iso | en | de_CH |
dc.publisher | Elsevier | de_CH |
dc.relation.ispartof | Journal of Molecular Structure | de_CH |
dc.rights | Licence according to publishing contract | de_CH |
dc.subject | Quinolinium | de_CH |
dc.subject | π-conjugated compound | de_CH |
dc.subject | Organic crystals | de_CH |
dc.subject | Supramolecular interactions | de_CH |
dc.subject.ddc | 540: Chemie | de_CH |
dc.title | Organic styryl quinolinium crystal with aromatic anion bearing electron-rich vinyl group | de_CH |
dc.type | Beitrag in wissenschaftlicher Zeitschrift | de_CH |
dcterms.type | Text | de_CH |
zhaw.departement | School of Engineering | de_CH |
zhaw.organisationalunit | Institute of Computational Physics (ICP) | de_CH |
dc.identifier.doi | 10.1016/j.molstruc.2015.07.071 | de_CH |
zhaw.funding.eu | No | de_CH |
zhaw.originated.zhaw | Yes | de_CH |
zhaw.pages.end | 365 | de_CH |
zhaw.pages.start | 359 | de_CH |
zhaw.publication.status | publishedVersion | de_CH |
zhaw.volume | 1100 | de_CH |
zhaw.publication.review | Peer review (Publikation) | de_CH |
Appears in collections: | Publikationen School of Engineering |
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Lee, S.-H., Yoo, B.-W., Yun, H., Jazbinsek, M., & Kwon, O.-P. (2015). Organic styryl quinolinium crystal with aromatic anion bearing electron-rich vinyl group. Journal of Molecular Structure, 1100, 359–365. https://doi.org/10.1016/j.molstruc.2015.07.071
Lee, S.-H. et al. (2015) ‘Organic styryl quinolinium crystal with aromatic anion bearing electron-rich vinyl group’, Journal of Molecular Structure, 1100, pp. 359–365. Available at: https://doi.org/10.1016/j.molstruc.2015.07.071.
S.-H. Lee, B.-W. Yoo, H. Yun, M. Jazbinsek, and O.-P. Kwon, “Organic styryl quinolinium crystal with aromatic anion bearing electron-rich vinyl group,” Journal of Molecular Structure, vol. 1100, pp. 359–365, 2015, doi: 10.1016/j.molstruc.2015.07.071.
LEE, Seung-Heon, Ba-Wool YOO, Hoseop YUN, Mojca JAZBINSEK und O-Pil KWON, 2015. Organic styryl quinolinium crystal with aromatic anion bearing electron-rich vinyl group. Journal of Molecular Structure. 2015. Bd. 1100, S. 359–365. DOI 10.1016/j.molstruc.2015.07.071
Lee, Seung-Heon, Ba-Wool Yoo, Hoseop Yun, Mojca Jazbinsek, and O-Pil Kwon. 2015. “Organic Styryl Quinolinium Crystal with Aromatic Anion Bearing Electron-Rich Vinyl Group.” Journal of Molecular Structure 1100: 359–65. https://doi.org/10.1016/j.molstruc.2015.07.071.
Lee, Seung-Heon, et al. “Organic Styryl Quinolinium Crystal with Aromatic Anion Bearing Electron-Rich Vinyl Group.” Journal of Molecular Structure, vol. 1100, 2015, pp. 359–65, https://doi.org/10.1016/j.molstruc.2015.07.071.
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