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  4. Publikationen School of Engineering
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dc.contributor.authorLee, Seung-Heon-
dc.contributor.authorLee, Gyeong-Hui-
dc.contributor.authorLee, Kang-Hyun-
dc.contributor.authorJazbinsek, Mojca-
dc.contributor.authorKang, Bong Joo-
dc.contributor.authorRotermund, Fabian-
dc.contributor.authorKwon, O-Pil-
dc.date.accessioned2018-09-18T14:02:46Z-
dc.date.available2018-09-18T14:02:46Z-
dc.date.issued2016-
dc.identifier.issn1528-7483de_CH
dc.identifier.issn1528-7505de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/10781-
dc.description.abstractWe report on a new morphological crystal engineering technique introducing in situ tailor-made additives for organic molecular crystals. In the crystal growing process, phenolic substrate molecules are transformed to in situ tailor-made phenolate additives by adding a small amount of base, without any additional synthetic and purification processes. To demonstrate the in situ tailor-made additive technique, phenolic OH1 (2-(3-(4-hydroxystyryl)-5,5-dimethylcyclohex-2-enylidene)malononitrile) crystal, exhibiting highly efficient nonlinear optical and terahertz generation responses, is chosen as substrate crystal. The in situ tailor-made additive molecules containing a phenolate group exhibit considerably different stereoselective interactions with specific crystal surfaces of phenolic substrate OH1 crystals compared to analogous conventional tailor-made additives. The stereospecific interactions result in a morphological change of the grown OH1 crystal more optimal for photonic applications. To show the usefulness of the in situ tailor-made additive technique for applications as well as for fundamental research, newly created parallel surfaces in rectangular rod-shaped OH1 crystals grown in the presence of tailor-made additive are used to demonstrate the THz wave generation by optical rectification, in which one single OH1 crystal can be used in two different optical configurations. Therefore, the in situ tailor-made additive technique is very useful for morphological crystal engineering in fundamental research and various practical applications.de_CH
dc.language.isoende_CH
dc.publisherAmerican Chemical Societyde_CH
dc.relation.ispartofCrystal Growth & Designde_CH
dc.rightsLicence according to publishing contractde_CH
dc.subject.ddc540: Chemiede_CH
dc.titleIn situ tailor-made additives for molecular crystals : a simple route to morphological crystal engineeringde_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementSchool of Engineeringde_CH
zhaw.organisationalunitInstitute of Computational Physics (ICP)de_CH
dc.identifier.doi10.1021/acs.cgd.6b00219de_CH
zhaw.funding.euNode_CH
zhaw.issue7de_CH
zhaw.originated.zhawYesde_CH
zhaw.pages.end3561de_CH
zhaw.pages.start3555de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume16de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
Appears in collections:Publikationen School of Engineering

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Lee, S.-H., Lee, G.-H., Lee, K.-H., Jazbinsek, M., Kang, B. J., Rotermund, F., & Kwon, O.-P. (2016). In situ tailor-made additives for molecular crystals : a simple route to morphological crystal engineering. Crystal Growth & Design, 16(7), 3555–3561. https://doi.org/10.1021/acs.cgd.6b00219
Lee, S.-H. et al. (2016) ‘In situ tailor-made additives for molecular crystals : a simple route to morphological crystal engineering’, Crystal Growth & Design, 16(7), pp. 3555–3561. Available at: https://doi.org/10.1021/acs.cgd.6b00219.
S.-H. Lee et al., “In situ tailor-made additives for molecular crystals : a simple route to morphological crystal engineering,” Crystal Growth & Design, vol. 16, no. 7, pp. 3555–3561, 2016, doi: 10.1021/acs.cgd.6b00219.
LEE, Seung-Heon, Gyeong-Hui LEE, Kang-Hyun LEE, Mojca JAZBINSEK, Bong Joo KANG, Fabian ROTERMUND und O-Pil KWON, 2016. In situ tailor-made additives for molecular crystals : a simple route to morphological crystal engineering. Crystal Growth & Design. 2016. Bd. 16, Nr. 7, S. 3555–3561. DOI 10.1021/acs.cgd.6b00219
Lee, Seung-Heon, Gyeong-Hui Lee, Kang-Hyun Lee, Mojca Jazbinsek, Bong Joo Kang, Fabian Rotermund, and O-Pil Kwon. 2016. “In Situ Tailor-Made Additives for Molecular Crystals : A Simple Route to Morphological Crystal Engineering.” Crystal Growth & Design 16 (7): 3555–61. https://doi.org/10.1021/acs.cgd.6b00219.
Lee, Seung-Heon, et al. “In Situ Tailor-Made Additives for Molecular Crystals : A Simple Route to Morphological Crystal Engineering.” Crystal Growth & Design, vol. 16, no. 7, 2016, pp. 3555–61, https://doi.org/10.1021/acs.cgd.6b00219.


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