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dc.contributor.authorGerber, Roman-
dc.contributor.authorFox, Thomas-
dc.contributor.authorFrech, Christian M.-
dc.date.accessioned2018-09-12T12:48:29Z-
dc.date.available2018-09-12T12:48:29Z-
dc.date.issued2010-
dc.identifier.issn0947-6539de_CH
dc.identifier.issn1521-3765de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/10469-
dc.description.abstractLittle and large! The aliphatic palladium(II) pincer hydride complex undergoes smooth dihydrogen evolution and formation of the stable palladium(II) hydroxide complex when an excess of water is added to a solution of the complex in THF. This reactivity is strikingly different when compared to its aromatic analogue and can be attributed to the stronger trans influence of the aliphatic pincer unit. The reaction is reversible and fast hydrogenolysis is observed.de_CH
dc.language.isoende_CH
dc.publisherWileyde_CH
dc.relation.ispartofChemistry - A European Journalde_CH
dc.rightsLicence according to publishing contractde_CH
dc.subject.ddc540: Chemiede_CH
dc.titleP Csp3 P and P Csp2 P palladium(II) hydride pincer complexes : small structural difference-large effect on reactivityde_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementLife Sciences und Facility Managementde_CH
dc.identifier.doi10.1002/chem.201000247de_CH
dc.identifier.pmid20455220de_CH
zhaw.funding.euNode_CH
zhaw.issue23de_CH
zhaw.originated.zhawNode_CH
zhaw.pages.end6775de_CH
zhaw.pages.start6771de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume16de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
Appears in collections:Publikationen Life Sciences und Facility Management

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Gerber, R., Fox, T., & Frech, Christian M. (2010). P Csp3 P and P Csp2 P palladium(II) hydride pincer complexes : small structural difference-large effect on reactivity. Chemistry - A European Journal, 16(23), 6771–6775. https://doi.org/10.1002/chem.201000247
Gerber, R., Fox, T. and Frech, Christian M. (2010) ‘P Csp3 P and P Csp2 P palladium(II) hydride pincer complexes : small structural difference-large effect on reactivity’, Chemistry - A European Journal, 16(23), pp. 6771–6775. Available at: https://doi.org/10.1002/chem.201000247.
R. Gerber, T. Fox, and Christian M. Frech, “P Csp3 P and P Csp2 P palladium(II) hydride pincer complexes : small structural difference-large effect on reactivity,” Chemistry - A European Journal, vol. 16, no. 23, pp. 6771–6775, 2010, doi: 10.1002/chem.201000247.
GERBER, Roman, Thomas FOX und Christian M. FRECH, 2010. P Csp3 P and P Csp2 P palladium(II) hydride pincer complexes : small structural difference-large effect on reactivity. Chemistry - A European Journal. 2010. Bd. 16, Nr. 23, S. 6771–6775. DOI 10.1002/chem.201000247
Gerber, Roman, Thomas Fox, and Christian M. Frech. 2010. “P Csp3 P and P Csp2 P palladium(II) Hydride Pincer Complexes : Small Structural Difference-Large Effect on Reactivity.” Chemistry - A European Journal 16 (23): 6771–75. https://doi.org/10.1002/chem.201000247.
Gerber, Roman, et al. “P Csp3 P and P Csp2 P palladium(II) Hydride Pincer Complexes : Small Structural Difference-Large Effect on Reactivity.” Chemistry - A European Journal, vol. 16, no. 23, 2010, pp. 6771–75, https://doi.org/10.1002/chem.201000247.


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