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https://doi.org/10.21256/zhaw-3561
Publikationstyp: | Beitrag in wissenschaftlicher Zeitschrift |
Art der Begutachtung: | Peer review (Publikation) |
Titel: | Incorporation of a FRET dye pair into mesoporous materials : a comparison of fluorescence spectra, FRET activity and dye accessibility |
Autor/-in: | Widmer, Susanne Reber, Michael J. Müller, Patrick Housecroft, Catherine E. Constable, Edwin C. Rossi, René M. Brühwiler, Dominik Scherer, Lukas J. Boesel, Luciano F. |
DOI: | 10.21256/zhaw-3561 10.1039/C5AN00850F |
Erschienen in: | The Analyst |
Band(Heft): | 140 |
Heft: | 15 |
Seite(n): | 5324 |
Seiten bis: | 5334 |
Erscheinungsdatum: | 2015 |
Verlag / Hrsg. Institution: | Royal Society of Chemistry |
ISSN: | 0003-2654 1364-5528 |
Sprache: | Englisch |
Schlagwörter: | Sensor; Mesopores; SBA-15; Ammonia |
Fachgebiet (DDC): | 540: Chemie |
Zusammenfassung: | Fluorescein and rhodamine B modified mesoporous silica particles were synthesized by post-grafting and co-condensation approaches. The materials exhibited different pore size distributions, particle shapes and sizes. The materials were characterized by nitrogen sorption, scanning electron microscopy and fluorescence spectroscopy. The Förster resonance energy transfer between the selected dye pair was explored for the different materials by exposure to various concentrations of gaseous ammonia. A logarithmic increase in rhodamine B emission with increasing ammonia concentration was observed for both post-grafted and co-condensed materials. The dye accessibility by ammonia gas in the silica framework of mesoporous materials was evaluated by using a flow cell gas sensor setup built in-house. Response to ammonia gas and recovery with nitrogen gas are explained by comparing the structure properties and dye loading of the materials. The post-grafted dye modified silica showed better performance in terms of reversibility and recovery. |
Weitere Angaben: | Open Access Artikel |
URI: | https://digitalcollection.zhaw.ch/handle/11475/2604 |
Volltext Version: | Publizierte Version |
Lizenz (gemäss Verlagsvertrag): | CC BY 3.0: Namensnennung 3.0 Unported |
Departement: | Life Sciences und Facility Management |
Organisationseinheit: | Institut für Chemie und Biotechnologie (ICBT) |
Publiziert im Rahmen des ZHAW-Projekts: | Molecular Alignment Chips (MACs) |
Enthalten in den Sammlungen: | Publikationen Life Sciences und Facility Management |
Dateien zu dieser Ressource:
Datei | Beschreibung | Größe | Format | |
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2015_Widmer_Incorporation of a FRET dye pair_The Analyst.pdf | 2.73 MB | Adobe PDF | Öffnen/Anzeigen |
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Widmer, S., Reber, M. J., Müller, P., Housecroft, C. E., Constable, E. C., Rossi, R. M., Brühwiler, D., Scherer, L. J., & Boesel, L. F. (2015). Incorporation of a FRET dye pair into mesoporous materials : a comparison of fluorescence spectra, FRET activity and dye accessibility. The Analyst, 140(15), 5324–5334. https://doi.org/10.21256/zhaw-3561
Widmer, S. et al. (2015) ‘Incorporation of a FRET dye pair into mesoporous materials : a comparison of fluorescence spectra, FRET activity and dye accessibility’, The Analyst, 140(15), pp. 5324–5334. Available at: https://doi.org/10.21256/zhaw-3561.
S. Widmer et al., “Incorporation of a FRET dye pair into mesoporous materials : a comparison of fluorescence spectra, FRET activity and dye accessibility,” The Analyst, vol. 140, no. 15, pp. 5324–5334, 2015, doi: 10.21256/zhaw-3561.
WIDMER, Susanne, Michael J. REBER, Patrick MÜLLER, Catherine E. HOUSECROFT, Edwin C. CONSTABLE, René M. ROSSI, Dominik BRÜHWILER, Lukas J. SCHERER und Luciano F. BOESEL, 2015. Incorporation of a FRET dye pair into mesoporous materials : a comparison of fluorescence spectra, FRET activity and dye accessibility. The Analyst. 2015. Bd. 140, Nr. 15, S. 5324–5334. DOI 10.21256/zhaw-3561
Widmer, Susanne, Michael J. Reber, Patrick Müller, Catherine E. Housecroft, Edwin C. Constable, René M. Rossi, Dominik Brühwiler, Lukas J. Scherer, and Luciano F. Boesel. 2015. “Incorporation of a FRET Dye Pair into Mesoporous Materials : A Comparison of Fluorescence Spectra, FRET Activity and Dye Accessibility.” The Analyst 140 (15): 5324–34. https://doi.org/10.21256/zhaw-3561.
Widmer, Susanne, et al. “Incorporation of a FRET Dye Pair into Mesoporous Materials : A Comparison of Fluorescence Spectra, FRET Activity and Dye Accessibility.” The Analyst, vol. 140, no. 15, 2015, pp. 5324–34, https://doi.org/10.21256/zhaw-3561.
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