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Publikationstyp: Konferenz: Paper
Art der Begutachtung: Peer review (Publikation)
Titel: Inactivation of palladium-based oxygen scavenger system by volatile sulphur compounds present in the headspace of packaged food
Autor/-in: Röcker, Bettina
Rüegg, Nadine
Glöss, Alexia N.
Yeretzian, Chahan
Yildirim, Selçuk
DOI: 10.21256/zhaw-4261
10.1002/pts.2220
Erschienen in: Packaging Technology and Science
Tagungsband: Packaging Technology and Science
Band(Heft): 30
Heft: 8
Seite(n): 427
Seiten bis: 442
Angaben zur Konferenz: 20th IAPRI World Conference on Packaging 2016, Sao Paulo, 12-15 June 2016
Erscheinungsdatum: 2017
Verlag / Hrsg. Institution: Wiley
ISSN: 0894-3214
Sprache: Englisch
Schlagwörter: Volatile sulphur compounds; Palladium; Oxygen scavengers; Catalyst poisoning
Fachgebiet (DDC): 664: Lebensmitteltechnologie
Zusammenfassung: An oxygen scavenger based on a catalytic system with palladium (CSP) was recently developed to remove oxygen in food packagings. Although the CSP worked with various types of food, with some foods, an inhibition of the CSP was observed. Because such catalytic systems are susceptible to poisoning by sulfurcontaining compounds, the aim of this study was to understand the inactivation of palladium-based catalysts in presence of foods containing volatile sulfur compounds (VSCs). To achieve this, the oxygen scavenging activity (OSA) of the CSP was evaluated in presence of selected food products. Afterwards, VSCs mainly present in these foods were exposed to the CSP, and the influence on the OSA was evaluated. Finally, headspace analysis was performed with the diluted VSCs and with the packaged food products using proton transfer reaction time-of-flight mass spectrometry. It was found that the catalytic activity of the CSP was inhibited when VSCs were present in the headspace in concentrations ranging between 10.8–36.0 ppbv (dimethyl sulfide, DMS), 1.2–7.2 ppbv (dimethyl disulfide), 0.7–0.9 ppbv (dimethyl trisulfide), 2.1–5.8 ppbv methional) and 4.6–24.5 ppbv (furfuryl thiol). It was concluded that in packaged roast beef and cheese, DMS may be the compound mainly responsible for the inactivation of the CSP. In packagings containing ham, the key compounds were hydrogen sulfide and methanethiol; in peanuts, it was methanethiol; and in par-baked buns, an accumulation of methional, DMS, butanethiol and methionol. When potato chips were packaged, it was demonstrated that when VSCs are present in low concentrations, oxygen can still be scavenged at a reduced OSA.
URI: https://digitalcollection.zhaw.ch/handle/11475/7082
Volltext Version: Eingereichte Version
Lizenz (gemäss Verlagsvertrag): Lizenz gemäss Verlagsvertrag
Departement: Life Sciences und Facility Management
Organisationseinheit: Institut für Lebensmittel- und Getränkeinnovation (ILGI)
Enthalten in den Sammlungen:Publikationen Life Sciences und Facility Management

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Röcker, B., Rüegg, N., Glöss, A. N., Yeretzian, C., & Yildirim, S. (2017). Inactivation of palladium-based oxygen scavenger system by volatile sulphur compounds present in the headspace of packaged food [Conference paper]. Packaging Technology and Science, 30(8), 427–442. https://doi.org/10.21256/zhaw-4261
Röcker, B. et al. (2017) ‘Inactivation of palladium-based oxygen scavenger system by volatile sulphur compounds present in the headspace of packaged food’, in Packaging Technology and Science. Wiley, pp. 427–442. Available at: https://doi.org/10.21256/zhaw-4261.
B. Röcker, N. Rüegg, A. N. Glöss, C. Yeretzian, and S. Yildirim, “Inactivation of palladium-based oxygen scavenger system by volatile sulphur compounds present in the headspace of packaged food,” in Packaging Technology and Science, 2017, vol. 30, no. 8, pp. 427–442. doi: 10.21256/zhaw-4261.
RÖCKER, Bettina, Nadine RÜEGG, Alexia N. GLÖSS, Chahan YERETZIAN und Selçuk YILDIRIM, 2017. Inactivation of palladium-based oxygen scavenger system by volatile sulphur compounds present in the headspace of packaged food. In: Packaging Technology and Science. Conference paper. Wiley. 2017. S. 427–442
Röcker, Bettina, Nadine Rüegg, Alexia N. Glöss, Chahan Yeretzian, and Selçuk Yildirim. 2017. “Inactivation of Palladium-Based Oxygen Scavenger System by Volatile Sulphur Compounds Present in the Headspace of Packaged Food.” Conference paper. In Packaging Technology and Science, 30:427–42. Wiley. https://doi.org/10.21256/zhaw-4261.
Röcker, Bettina, et al. “Inactivation of Palladium-Based Oxygen Scavenger System by Volatile Sulphur Compounds Present in the Headspace of Packaged Food.” Packaging Technology and Science, vol. 30, no. 8, Wiley, 2017, pp. 427–42, https://doi.org/10.21256/zhaw-4261.


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