Publication type: | Article in scientific journal |
Type of review: | Peer review (publication) |
Title: | Partial separation of fullerenes by gradient sublimation |
Authors: | Yeretzian, Chahan Wiley, John B. Holczer, Karoly Su, Tim Nguyen, Song Kaner, Richard B. Whetten, Robert L. |
DOI: | 10.1021/j100141a033 |
Published in: | The Journal of Physical Chemistry |
Volume(Issue): | 97 |
Issue: | 39 |
Page(s): | 10097 |
Pages to: | 10101 |
Issue Date: | 1993 |
Publisher / Ed. Institution: | American Chemical Society |
Publisher / Ed. Institution: | Washington |
ISSN: | 0022-3654 1541-5740 |
Language: | English |
Subjects: | Sublimation; Fullerenes |
Subject (DDC): | 540: Chemistry |
Abstract: | An experimental technique is investigated to separate/enrich fullerenes or metallofullerenes, exploiting differences in sublimation temperatures without the use of solvents. Fullerenes are sublimed out of the soot and deposited on a quartz rod along a temperature gradient (gradient sublimation). In a position-sensitive experiment the composition of the deposit on the rod is monitored by laser-desorption mass spectrometry. Strongly enriched regions containing specific fullerene molecules (i.e., C84 or La@ C82) are observed. Furthermore, C74, which could not be extracted from the soot by organic solvents, sublimes out of the soot. |
URI: | https://digitalcollection.zhaw.ch/handle/11475/5453 |
Fulltext version: | Published version |
License (according to publishing contract): | Licence according to publishing contract |
Departement: | Life Sciences and Facility Management |
Organisational Unit: | Institute of Chemistry and Biotechnology (ICBT) |
Appears in collections: | Publikationen Life Sciences und Facility Management |
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Yeretzian, C., Wiley, J. B., Holczer, K., Su, T., Nguyen, S., Kaner, R. B., & Whetten, R. L. (1993). Partial separation of fullerenes by gradient sublimation. The Journal of Physical Chemistry, 97(39), 10097–10101. https://doi.org/10.1021/j100141a033
Yeretzian, C. et al. (1993) ‘Partial separation of fullerenes by gradient sublimation’, The Journal of Physical Chemistry, 97(39), pp. 10097–10101. Available at: https://doi.org/10.1021/j100141a033.
C. Yeretzian et al., “Partial separation of fullerenes by gradient sublimation,” The Journal of Physical Chemistry, vol. 97, no. 39, pp. 10097–10101, 1993, doi: 10.1021/j100141a033.
YERETZIAN, Chahan, John B. WILEY, Karoly HOLCZER, Tim SU, Song NGUYEN, Richard B. KANER und Robert L. WHETTEN, 1993. Partial separation of fullerenes by gradient sublimation. The Journal of Physical Chemistry. 1993. Bd. 97, Nr. 39, S. 10097–10101. DOI 10.1021/j100141a033
Yeretzian, Chahan, John B. Wiley, Karoly Holczer, Tim Su, Song Nguyen, Richard B. Kaner, and Robert L. Whetten. 1993. “Partial Separation of Fullerenes by Gradient Sublimation.” The Journal of Physical Chemistry 97 (39): 10097–101. https://doi.org/10.1021/j100141a033.
Yeretzian, Chahan, et al. “Partial Separation of Fullerenes by Gradient Sublimation.” The Journal of Physical Chemistry, vol. 97, no. 39, 1993, pp. 10097–101, https://doi.org/10.1021/j100141a033.
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