| Publication type: | Article in scientific journal |
| Type of review: | Peer review (publication) |
| Title: | Breakdown of the born-oppenheimer approximation in ZEKE states of Ag2 |
| Authors: | Yeretzian, Chahan Hermann, Robert H. Ungar, Horst Selzle, Heinrich L. Schlag, Edward W. Lin, Sheng H. |
| DOI: | 10.1016/0009-2614(95)00441-6 |
| Published in: | Chemical Physics Letters |
| Volume(Issue): | 239 |
| Issue: | 1-3 |
| Page(s): | 61 |
| Pages to: | 66 |
| Issue Date: | 9-Jun-1995 |
| Publisher / Ed. Institution: | Elsevier |
| Publisher / Ed. Institution: | Amsterdam |
| ISSN: | 0009-2614 1873-4448 |
| Language: | English |
| Subjects: | Zeke; Silver cluster; Born-oppenheimer approximation |
| Subject (DDC): | 540: Chemistry |
| Abstract: | Recently we reported on vibrationally resolved spectra of the ionic ground state of Ag2+ via ZEKE spectroscopy. The vibronic intensity distributions could not be interpreted within the Franck-Condon scheme. Here, we show that it is possible to overcome this discrepancy by invoking the breakdown of the Born-Oppenheimer approximation in the ZEKE states of silver dimer. A comparison of the spectral structure of the direct ion signal with simultaneously recorded ZEKE band profiles further illustrates this non-Franck-Condon behavior. |
| URI: | https://digitalcollection.zhaw.ch/handle/11475/5339 |
| Fulltext version: | Published version |
| License (according to publishing contract): | Licence according to publishing contract |
| Departement: | Life Sciences and Facility Management |
| Appears in collections: | Publikationen Life Sciences und Facility Management |
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Yeretzian, C., Hermann, R. H., Ungar, H., Selzle, H. L., Schlag, E. W., & Lin, S. H. (1995). Breakdown of the born-oppenheimer approximation in ZEKE states of Ag2. Chemical Physics Letters, 239(1-3), 61–66. https://doi.org/10.1016/0009-2614(95)00441-6
Yeretzian, C. et al. (1995) ‘Breakdown of the born-oppenheimer approximation in ZEKE states of Ag2’, Chemical Physics Letters, 239(1-3), pp. 61–66. Available at: https://doi.org/10.1016/0009-2614(95)00441-6.
C. Yeretzian, R. H. Hermann, H. Ungar, H. L. Selzle, E. W. Schlag, and S. H. Lin, “Breakdown of the born-oppenheimer approximation in ZEKE states of Ag2,” Chemical Physics Letters, vol. 239, no. 1-3, pp. 61–66, Jun. 1995, doi: 10.1016/0009-2614(95)00441-6.
YERETZIAN, Chahan, Robert H. HERMANN, Horst UNGAR, Heinrich L. SELZLE, Edward W. SCHLAG und Sheng H. LIN, 1995. Breakdown of the born-oppenheimer approximation in ZEKE states of Ag2. Chemical Physics Letters. 9 Juni 1995. Bd. 239, Nr. 1-3, S. 61–66. DOI 10.1016/0009-2614(95)00441-6
Yeretzian, Chahan, Robert H. Hermann, Horst Ungar, Heinrich L. Selzle, Edward W. Schlag, and Sheng H. Lin. 1995. “Breakdown of the Born-Oppenheimer Approximation in ZEKE States of Ag2.” Chemical Physics Letters 239 (1-3): 61–66. https://doi.org/10.1016/0009-2614(95)00441-6.
Yeretzian, Chahan, et al. “Breakdown of the Born-Oppenheimer Approximation in ZEKE States of Ag2.” Chemical Physics Letters, vol. 239, no. 1-3, June 1995, pp. 61–66, https://doi.org/10.1016/0009-2614(95)00441-6.
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