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Publikationstyp: Beitrag in wissenschaftlicher Zeitschrift
Art der Begutachtung: Peer review (Publikation)
Titel: Investigation of silica particle growth by incorporation of a pyrene fluorescent probe
Autor/-in: Walther, Fabian
Brühwiler, Dominik
et. al: No
DOI: 10.1016/j.colsurfa.2024.133234
10.21256/zhaw-29683
Erschienen in: Colloids and Surfaces A: Physicochemical and Engineering Aspects
Band(Heft): 685
Heft: 133234
Erscheinungsdatum: 2024
Verlag / Hrsg. Institution: Elsevier
ISSN: 0927-7757
Sprache: Englisch
Schlagwörter: Stöber; Silica; Particle; Fluorescence; Excimer; Pyrene; Growth; Aggregation; Monomer addition
Fachgebiet (DDC): 540: Chemie
Zusammenfassung: The growth of silica particles synthesized by the Stöber method was investigated by the co-condensation of pyrene sulfonyl chloride (PySCl) coupled to (3-aminopropyl)triethoxysilane (APTES). Growth by monomer addition could be distinguished from growth by aggregation based on the intensity of the pyrene excimer emission of the resulting particles. The influence of the base concentration, water/ethanol ratio, solvent, temperature, and type of silica precursor was studied. At high hydrolysis rates, the growth occurred primarily by aggregation, whereas growth by monomer addition was predominant at low hydrolysis rates. The results were confirmed by evaluating the accessibility of the co-condensed pyrene moieties and by determining the porosity of the particles.
URI: https://digitalcollection.zhaw.ch/handle/11475/29683
Volltext Version: Publizierte Version
Lizenz (gemäss Verlagsvertrag): CC BY 4.0: Namensnennung 4.0 International
Departement: Life Sciences und Facility Management
Organisationseinheit: Institut für Chemie und Biotechnologie (ICBT)
Enthalten in den Sammlungen:Publikationen Life Sciences und Facility Management

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Walther, F., & Brühwiler, D. (2024). Investigation of silica particle growth by incorporation of a pyrene fluorescent probe. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 685(133234). https://doi.org/10.1016/j.colsurfa.2024.133234
Walther, F. and Brühwiler, D. (2024) ‘Investigation of silica particle growth by incorporation of a pyrene fluorescent probe’, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 685(133234). Available at: https://doi.org/10.1016/j.colsurfa.2024.133234.
F. Walther and D. Brühwiler, “Investigation of silica particle growth by incorporation of a pyrene fluorescent probe,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 685, no. 133234, 2024, doi: 10.1016/j.colsurfa.2024.133234.
WALTHER, Fabian und Dominik BRÜHWILER, 2024. Investigation of silica particle growth by incorporation of a pyrene fluorescent probe. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2024. Bd. 685, Nr. 133234. DOI 10.1016/j.colsurfa.2024.133234
Walther, Fabian, and Dominik Brühwiler. 2024. “Investigation of Silica Particle Growth by Incorporation of a Pyrene Fluorescent Probe.” Colloids and Surfaces A: Physicochemical and Engineering Aspects 685 (133234). https://doi.org/10.1016/j.colsurfa.2024.133234.
Walther, Fabian, and Dominik Brühwiler. “Investigation of Silica Particle Growth by Incorporation of a Pyrene Fluorescent Probe.” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 685, no. 133234, 2024, https://doi.org/10.1016/j.colsurfa.2024.133234.


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