| Publikationstyp: | Beitrag in wissenschaftlicher Zeitschrift |
| Art der Begutachtung: | Peer review (Publikation) |
| Titel: | Evolution of self-organized microcapsules with variable conductivities from self-assembled nanoparticles at interfaces |
| Autor/-in: | Mihali, Voichita Honciuc, Andrei |
| et. al: | No |
| DOI: | 10.1021/acsnano.8b09625 |
| Erschienen in: | ACS Nano |
| Band(Heft): | 13 |
| Heft: | 3 |
| Seite(n): | 3483 |
| Seiten bis: | 3491 |
| Erscheinungsdatum: | 2019 |
| Verlag / Hrsg. Institution: | American Chemical Society |
| ISSN: | 1936-0851 1936-086X |
| Sprache: | Englisch |
| Schlagwörter: | PEDOT microcapsule; Pickering emulsion; Cooperative doping; Interfacial polymerization; Semiconductive Janus nanoparticle |
| Fachgebiet (DDC): | 540: Chemie |
| Zusammenfassung: | Self-organization dramatically affects the surface properties of materials on a macroscopic scale, such as wettability and adhesion. Fundamentally, it is equally interesting when self-organization at the nanoscale affects the bulk properties and thus provides a means to engineer the optoelectronic properties of the materials on larger scales. In this work, we report the evolution of conductive self-organized polymer microcapsules from a monomer emulsion droplet stabilized by a monolayer of conductive Janus nanoparticles (JNPs) via a mechanism resembling morphogenesis. The wall of the resulting conductive microcapsule has a honeycomb-like structure with highly oriented JNPs occupying each hollow cell. The JNPs consist of an electrically conductive lobe and an insulating lobe; because of their orientation and presence in the honeycomb, the conductivity of the microcapsule is greatly enhanced as compared to that of each of the constituting materials. This method can be universally applied to induce self-organization in conductive polymers forming by oxidative addition. |
| URI: | https://digitalcollection.zhaw.ch/handle/11475/17889 |
| Volltext Version: | Publizierte Version |
| Lizenz (gemäss Verlagsvertrag): | Lizenz gemäss Verlagsvertrag |
| Departement: | Life Sciences und Facility Management |
| Organisationseinheit: | Institut für Chemie und Biotechnologie (ICBT) |
| Enthalten in den Sammlungen: | Publikationen Life Sciences und Facility Management |
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Zur Langanzeige
Mihali, V., & Honciuc, A. (2019). Evolution of self-organized microcapsules with variable conductivities from self-assembled nanoparticles at interfaces. ACS Nano, 13(3), 3483–3491. https://doi.org/10.1021/acsnano.8b09625
Mihali, V. and Honciuc, A. (2019) ‘Evolution of self-organized microcapsules with variable conductivities from self-assembled nanoparticles at interfaces’, ACS Nano, 13(3), pp. 3483–3491. Available at: https://doi.org/10.1021/acsnano.8b09625.
V. Mihali and A. Honciuc, “Evolution of self-organized microcapsules with variable conductivities from self-assembled nanoparticles at interfaces,” ACS Nano, vol. 13, no. 3, pp. 3483–3491, 2019, doi: 10.1021/acsnano.8b09625.
MIHALI, Voichita und Andrei HONCIUC, 2019. Evolution of self-organized microcapsules with variable conductivities from self-assembled nanoparticles at interfaces. ACS Nano. 2019. Bd. 13, Nr. 3, S. 3483–3491. DOI 10.1021/acsnano.8b09625
Mihali, Voichita, and Andrei Honciuc. 2019. “Evolution of Self-Organized Microcapsules with Variable Conductivities from Self-Assembled Nanoparticles at Interfaces.” ACS Nano 13 (3): 3483–91. https://doi.org/10.1021/acsnano.8b09625.
Mihali, Voichita, and Andrei Honciuc. “Evolution of Self-Organized Microcapsules with Variable Conductivities from Self-Assembled Nanoparticles at Interfaces.” ACS Nano, vol. 13, no. 3, 2019, pp. 3483–91, https://doi.org/10.1021/acsnano.8b09625.
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