| Publikationstyp: | Beitrag in wissenschaftlicher Zeitschrift |
| Art der Begutachtung: | Peer review (Publikation) |
| Titel: | Elastic and inelastic electron tunneling spectroscopy of a new rectifying monolayer |
| Autor/-in: | Honciuc, Andrei Metzger, Robert M. Gong, Aijun Spangler, Charles W. |
| DOI: | 10.1021/ja068729g |
| Erschienen in: | Journal of the American Chemical Society |
| Band(Heft): | 129 |
| Heft: | 26 |
| Seite(n): | 8310 |
| Seiten bis: | 8319 |
| Erscheinungsdatum: | 2007 |
| Verlag / Hrsg. Institution: | American Chemical Society |
| ISSN: | 0002-7863 1520-5126 |
| Sprache: | Englisch |
| Fachgebiet (DDC): | 540: Chemie |
| Zusammenfassung: | Rectification of electrical current was observed in a Langmuir-Schaefer monolayer of fullerene-bis[ethylthio-tetrakis(3,4-dibutyl-2-thiophene-5-ethenyl)-5-bromo-3,4-dibutyl-2-thiophene] malonate, Au electrodes at room temperature (there are two regimes of asymmetry, at lower bias, i.e., between 0 and +/-2 V, and at higher bias), and also between Pb and Al electrodes at 4.2 K. The latter experiment was coupled with second harmonic detection of the second derivative of the current with respect to voltage (d2I/dV2). The d2I/dV2 spectrum shows intramolecular vibrations, and also two antisymmetric broad bands, centered at +/-0.65 V, due to resonant electron tunneling between the Fermi level(s) of the electrodes and the lowest unoccupied molecular orbital of the molecule. |
| URI: | https://digitalcollection.zhaw.ch/handle/11475/13762 |
| Volltext Version: | Publizierte Version |
| Lizenz (gemäss Verlagsvertrag): | Lizenz gemäss Verlagsvertrag |
| Departement: | Life Sciences und Facility Management |
| Enthalten in den Sammlungen: | Publikationen Life Sciences und Facility Management |
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Honciuc, A., Metzger, R. M., Gong, A., & Spangler, C. W. (2007). Elastic and inelastic electron tunneling spectroscopy of a new rectifying monolayer. Journal of the American Chemical Society, 129(26), 8310–8319. https://doi.org/10.1021/ja068729g
Honciuc, A. et al. (2007) ‘Elastic and inelastic electron tunneling spectroscopy of a new rectifying monolayer’, Journal of the American Chemical Society, 129(26), pp. 8310–8319. Available at: https://doi.org/10.1021/ja068729g.
A. Honciuc, R. M. Metzger, A. Gong, and C. W. Spangler, “Elastic and inelastic electron tunneling spectroscopy of a new rectifying monolayer,” Journal of the American Chemical Society, vol. 129, no. 26, pp. 8310–8319, 2007, doi: 10.1021/ja068729g.
HONCIUC, Andrei, Robert M. METZGER, Aijun GONG und Charles W. SPANGLER, 2007. Elastic and inelastic electron tunneling spectroscopy of a new rectifying monolayer. Journal of the American Chemical Society. 2007. Bd. 129, Nr. 26, S. 8310–8319. DOI 10.1021/ja068729g
Honciuc, Andrei, Robert M. Metzger, Aijun Gong, and Charles W. Spangler. 2007. “Elastic and Inelastic Electron Tunneling Spectroscopy of a New Rectifying Monolayer.” Journal of the American Chemical Society 129 (26): 8310–19. https://doi.org/10.1021/ja068729g.
Honciuc, Andrei, et al. “Elastic and Inelastic Electron Tunneling Spectroscopy of a New Rectifying Monolayer.” Journal of the American Chemical Society, vol. 129, no. 26, 2007, pp. 8310–19, https://doi.org/10.1021/ja068729g.
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