| Publikationstyp: | Beitrag in wissenschaftlicher Zeitschrift |
| Art der Begutachtung: | Peer review (Publikation) |
| Titel: | Mass spectrometric assay of polymerization catalysts for combinational screening |
| Autor/-in: | Hinderling, Christian Chen, Peter |
| DOI: | 10.1016/S1387-3806(99)00229-8 |
| Erschienen in: | International Journal of Mass Spectrometry |
| Band(Heft): | 195-196 |
| Seite(n): | 377 |
| Seiten bis: | 383 |
| Erscheinungsdatum: | 2000 |
| Verlag / Hrsg. Institution: | Elsevier |
| ISSN: | 1387-3806 1873-2798 |
| Sprache: | Englisch |
| Schlagwörter: | Catalyst; Screening |
| Fachgebiet (DDC): | 660: Technische Chemie |
| Zusammenfassung: | Electrospray ionization mass spectrometry of a homogeneous Ziegler-Natta polymerization catalyzed by a Pd(II) diimine complex shows two distinct distributions of metal-bound oligomeric ions corresponding to catalytic centers which have not undergone chain transfer and those that have. A fit of two distributions by numerical integration of the kinetic equations describing the polymerization gives the absolute rates for initiation, propagation, and chain transfer in the polymerization reaction, from which the bulk polymer properties can be predicted. The mass spectrometric method requires mg quantities of catalyst, requires only a few minutes, and is suitable for both pooled and parallel screens of catalyst libraries. |
| URI: | https://digitalcollection.zhaw.ch/handle/11475/13663 |
| Volltext Version: | Publizierte Version |
| Lizenz (gemäss Verlagsvertrag): | Lizenz gemäss Verlagsvertrag |
| Departement: | Life Sciences und Facility Management |
| Organisationseinheit: | Institut für Chemie und Biotechnologie (ICBT) |
| Enthalten in den Sammlungen: | Publikationen Life Sciences und Facility Management |
Dateien zu dieser Ressource:
Es gibt keine Dateien zu dieser Ressource.
Zur Langanzeige
Hinderling, C., & Chen, P. (2000). Mass spectrometric assay of polymerization catalysts for combinational screening. International Journal of Mass Spectrometry, 195-196, 377–383. https://doi.org/10.1016/S1387-3806(99)00229-8
Hinderling, C. and Chen, P. (2000) ‘Mass spectrometric assay of polymerization catalysts for combinational screening’, International Journal of Mass Spectrometry, 195-196, pp. 377–383. Available at: https://doi.org/10.1016/S1387-3806(99)00229-8.
C. Hinderling and P. Chen, “Mass spectrometric assay of polymerization catalysts for combinational screening,” International Journal of Mass Spectrometry, vol. 195-196, pp. 377–383, 2000, doi: 10.1016/S1387-3806(99)00229-8.
HINDERLING, Christian und Peter CHEN, 2000. Mass spectrometric assay of polymerization catalysts for combinational screening. International Journal of Mass Spectrometry. 2000. Bd. 195-196, S. 377–383. DOI 10.1016/S1387-3806(99)00229-8
Hinderling, Christian, and Peter Chen. 2000. “Mass Spectrometric Assay of Polymerization Catalysts for Combinational Screening.” International Journal of Mass Spectrometry 195-196: 377–83. https://doi.org/10.1016/S1387-3806(99)00229-8.
Hinderling, Christian, and Peter Chen. “Mass Spectrometric Assay of Polymerization Catalysts for Combinational Screening.” International Journal of Mass Spectrometry, vol. 195-196, 2000, pp. 377–83, https://doi.org/10.1016/S1387-3806(99)00229-8.
Alle Ressourcen in diesem Repository sind urheberrechtlich geschützt, soweit nicht anderweitig angezeigt.