| Publikationstyp: | Beitrag in wissenschaftlicher Zeitschrift |
| Art der Begutachtung: | Peer review (Publikation) |
| Titel: | Engineering of organic chromophores with large second-order optical nonlinearity and superior crystal growth ability |
| Autor/-in: | Chen, Honghong Ma, Qi Zhou, Yuqiao Yang, Zhou Jazbinsek, Mojca Bian, Yongzhong Ye, Ning Wang, Dong Cao, Hui He, Wanli |
| DOI: | 10.1021/acs.cgd.5b01216 |
| Erschienen in: | Crystal Growth & Design |
| Band(Heft): | 15 |
| Heft: | 11 |
| Seite(n): | 5560 |
| Seiten bis: | 5567 |
| Erscheinungsdatum: | 2015 |
| Verlag / Hrsg. Institution: | American Chemical Society |
| ISSN: | 1528-7483 1528-7505 |
| Sprache: | Englisch |
| Fachgebiet (DDC): | 540: Chemie |
| Zusammenfassung: | We present two D-π-A organic cationic core structures leading to highly efficient nonlinear optical (NLO) salts (E)-2-(4-(dimethylamino)styryl)-1,1,3-trimethyl-1H-benzo[e]indol-3-ium iodide (P–BI) and (E)-2-(2-(5-(dimethylamino)thiophen-2-yl) vinyl)-1,1,3 -trimethyl-1H-benzo[e]indol-3-ium iodide (S–BI). Single crystals of the above two materials were successfully obtained by the slow evaporation method. Two different polymorphic crystals of both P–BI and S–BI were obtained from different polar solvents. Kurtz powder tests revealed that the maximum second harmonic generation (SHG) efficiency of P–BI with monoclinic space group P21 is 1.14 times the benchmark DAST(4-N,N-dimethylamino-4,-N,-methylstilbazolium tosylate). Bulk single crystals of P–BI were obtained with size of up to 17.0 × 6.0 × 2.0 mm3 without using seed crystals. This demonstrates that this material exhibits great crystal growth ability along with a high second-order optical nonlinearity, making it a very attractive candidate for NLO applications such as electro-optics and THz-wave generation. |
| URI: | https://digitalcollection.zhaw.ch/handle/11475/10778 |
| Volltext Version: | Publizierte Version |
| Lizenz (gemäss Verlagsvertrag): | Lizenz gemäss Verlagsvertrag |
| Departement: | School of Engineering |
| Organisationseinheit: | Institute of Computational Physics (ICP) |
| Enthalten in den Sammlungen: | Publikationen School of Engineering |
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Chen, H., Ma, Q., Zhou, Y., Yang, Z., Jazbinsek, M., Bian, Y., Ye, N., Wang, D., Cao, H., & He, W. (2015). Engineering of organic chromophores with large second-order optical nonlinearity and superior crystal growth ability. Crystal Growth & Design, 15(11), 5560–5567. https://doi.org/10.1021/acs.cgd.5b01216
Chen, H. et al. (2015) ‘Engineering of organic chromophores with large second-order optical nonlinearity and superior crystal growth ability’, Crystal Growth & Design, 15(11), pp. 5560–5567. Available at: https://doi.org/10.1021/acs.cgd.5b01216.
H. Chen et al., “Engineering of organic chromophores with large second-order optical nonlinearity and superior crystal growth ability,” Crystal Growth & Design, vol. 15, no. 11, pp. 5560–5567, 2015, doi: 10.1021/acs.cgd.5b01216.
CHEN, Honghong, Qi MA, Yuqiao ZHOU, Zhou YANG, Mojca JAZBINSEK, Yongzhong BIAN, Ning YE, Dong WANG, Hui CAO und Wanli HE, 2015. Engineering of organic chromophores with large second-order optical nonlinearity and superior crystal growth ability. Crystal Growth & Design. 2015. Bd. 15, Nr. 11, S. 5560–5567. DOI 10.1021/acs.cgd.5b01216
Chen, Honghong, Qi Ma, Yuqiao Zhou, Zhou Yang, Mojca Jazbinsek, Yongzhong Bian, Ning Ye, Dong Wang, Hui Cao, and Wanli He. 2015. “Engineering of Organic Chromophores with Large Second-Order Optical Nonlinearity and Superior Crystal Growth Ability.” Crystal Growth & Design 15 (11): 5560–67. https://doi.org/10.1021/acs.cgd.5b01216.
Chen, Honghong, et al. “Engineering of Organic Chromophores with Large Second-Order Optical Nonlinearity and Superior Crystal Growth Ability.” Crystal Growth & Design, vol. 15, no. 11, 2015, pp. 5560–67, https://doi.org/10.1021/acs.cgd.5b01216.
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