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dc.contributor.authorAgrawal, Divya-
dc.contributor.authorSchröder, Detlef-
dc.contributor.authorFrech, Christian M.-
dc.date.accessioned2018-08-28T14:47:32Z-
dc.date.available2018-08-28T14:47:32Z-
dc.date.issued2011-
dc.identifier.issn0276-7333de_CH
dc.identifier.issn1520-6041de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/9851-
dc.description.abstractElectrospray ionization mass spectrometry (ESI-MS) is used for monitoring the progress of the Suzuki–Miyaura cross-coupling reaction between bromobenzene and arylboronic acids using a palladium dichloro-bis(aminophosphine) complex as a precatalyst. The ESI-MS studies demonstrate that initiation of the catalytic reaction requires the presence of a base and that the selectivity for cross-coupling is favorable at elevated temperatures. Interestingly, after completion of the coupling reaction, the palladium is present as a dinuclear Pd0/PdII cluster, which still acts as an active catalyst when a new aliquot of reactants is added to the reaction mixture.de_CH
dc.language.isoende_CH
dc.publisherAmerican Chemical Societyde_CH
dc.relation.ispartofOrganometallicsde_CH
dc.rightsLicence according to publishing contractde_CH
dc.subject.ddc540: Chemiede_CH
dc.titleObservation of binuclear palladium clusters upon ESI-MS monitoring of the Suzuki–Miyaura cross-coupling catalyzed by a dichloro-bis(aminophosphine) complex of palladiumde_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementLife Sciences und Facility Managementde_CH
dc.identifier.doi10.1021/om200274zde_CH
zhaw.funding.euNode_CH
zhaw.issue13de_CH
zhaw.originated.zhawNode_CH
zhaw.pages.end3587de_CH
zhaw.pages.start3579de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume30de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
Appears in collections:Publikationen Life Sciences und Facility Management

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Agrawal, D., Schröder, D., & Frech, C. M. (2011). Observation of binuclear palladium clusters upon ESI-MS monitoring of the Suzuki–Miyaura cross-coupling catalyzed by a dichloro-bis(aminophosphine) complex of palladium. Organometallics, 30(13), 3579–3587. https://doi.org/10.1021/om200274z
Agrawal, D., Schröder, D. and Frech, C.M. (2011) ‘Observation of binuclear palladium clusters upon ESI-MS monitoring of the Suzuki–Miyaura cross-coupling catalyzed by a dichloro-bis(aminophosphine) complex of palladium’, Organometallics, 30(13), pp. 3579–3587. Available at: https://doi.org/10.1021/om200274z.
D. Agrawal, D. Schröder, and C. M. Frech, “Observation of binuclear palladium clusters upon ESI-MS monitoring of the Suzuki–Miyaura cross-coupling catalyzed by a dichloro-bis(aminophosphine) complex of palladium,” Organometallics, vol. 30, no. 13, pp. 3579–3587, 2011, doi: 10.1021/om200274z.
AGRAWAL, Divya, Detlef SCHRÖDER und Christian M. FRECH, 2011. Observation of binuclear palladium clusters upon ESI-MS monitoring of the Suzuki–Miyaura cross-coupling catalyzed by a dichloro-bis(aminophosphine) complex of palladium. Organometallics. 2011. Bd. 30, Nr. 13, S. 3579–3587. DOI 10.1021/om200274z
Agrawal, Divya, Detlef Schröder, and Christian M. Frech. 2011. “Observation of Binuclear Palladium Clusters upon ESI-MS Monitoring of the Suzuki–Miyaura Cross-Coupling Catalyzed by a Dichloro-Bis(aminophosphine) Complex of Palladium.” Organometallics 30 (13): 3579–87. https://doi.org/10.1021/om200274z.
Agrawal, Divya, et al. “Observation of Binuclear Palladium Clusters upon ESI-MS Monitoring of the Suzuki–Miyaura Cross-Coupling Catalyzed by a Dichloro-Bis(aminophosphine) Complex of Palladium.” Organometallics, vol. 30, no. 13, 2011, pp. 3579–87, https://doi.org/10.1021/om200274z.


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