Electronic structure effects in bimetallic MxN clusters : M = alkali, N = divalent metal

Yeretzian, Chahan

doi:10.1021/j100001a022

Publication type:	Article in scientific journal
Type of review:	Peer review (publication)
Title:	Electronic structure effects in bimetallic MxN clusters : M = alkali, N = divalent metal
Authors:	Yeretzian, Chahan
DOI:	10.1021/j100001a022
Published in:	The Journal of Physical Chemistry
Volume(Issue):	99
Issue:	1
Page(s):	123
Pages to:	130
Issue Date:	Jan-1995
Publisher / Ed. Institution:	American Chemical Society
Publisher / Ed. Institution:	Washington
ISSN:	0022-3654 1541-5740
Language:	English
Subjects:	Bimetallic clusters; Clusters; Metal
Subject (DDC):	540: Chemistry
Abstract:	Mass-spectral results on alkali clusters containing one host-atom with ns2 valence-shell configuration (Mg, Ca, Sr, Ba, Zn, Eu, and Yb) are presented. They allow uncoupling of the number of atoms in the cluster from the number of its valence electrons by probing with elements with more than one valence electron and different ionization potential and atomic radius. Prominent intensity maxima for specific cluster sizes are observed. Based on an electronic shell model, a systematic interpretation of the intensity maxima as a function of the incorporated heteroatom is presented. Although most of the gross features can be rationalized within a purely electronic model, a more refined analysis prompts one to geometric structure effects which have to be included to more fully describe the spectra.
URI:	https://digitalcollection.zhaw.ch/handle/11475/5452
Fulltext version:	Published version
License (according to publishing contract):	Licence according to publishing contract
Departement:	Life Sciences and Facility Management
Appears in collections:	Publikationen Life Sciences und Facility Management

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Yeretzian, C. (1995). Electronic structure effects in bimetallic MxN clusters : M = alkali, N = divalent metal. The Journal of Physical Chemistry, 99(1), 123–130. https://doi.org/10.1021/j100001a022

Yeretzian, C. (1995) ‘Electronic structure effects in bimetallic MxN clusters : M = alkali, N = divalent metal’, The Journal of Physical Chemistry, 99(1), pp. 123–130. Available at: https://doi.org/10.1021/j100001a022.

C. Yeretzian, “Electronic structure effects in bimetallic MxN clusters : M = alkali, N = divalent metal,” The Journal of Physical Chemistry, vol. 99, no. 1, pp. 123–130, Jan. 1995, doi: 10.1021/j100001a022.

YERETZIAN, Chahan, 1995. Electronic structure effects in bimetallic MxN clusters : M = alkali, N = divalent metal. The Journal of Physical Chemistry. Januar 1995. Bd. 99, Nr. 1, S. 123–130. DOI 10.1021/j100001a022

Yeretzian, Chahan. 1995. “Electronic Structure Effects in Bimetallic MxN Clusters : M = Alkali, N = Divalent Metal.” The Journal of Physical Chemistry 99 (1): 123–30. https://doi.org/10.1021/j100001a022.

Yeretzian, Chahan. “Electronic Structure Effects in Bimetallic MxN Clusters : M = Alkali, N = Divalent Metal.” The Journal of Physical Chemistry, vol. 99, no. 1, Jan. 1995, pp. 123–30, https://doi.org/10.1021/j100001a022.