| Publication type: | Article in scientific journal |
| Type of review: | Peer review (publication) |
| Title: | Endohedral rare-earth fullerene complexes |
| Authors: | Gillan, Edward G. Yeretzian, Chahan Min, Kyu S. Alvarez, Marcos M. Whetten, Robert L. Kaner, Richard B. |
| DOI: | 10.1021/j100196a006 |
| Published in: | The Journal of Physical Chemistry |
| Volume(Issue): | 96 |
| Issue: | 17 |
| Page(s): | 6869 |
| Pages to: | 6871 |
| Issue Date: | Aug-1992 |
| Publisher / Ed. Institution: | American Chemical Society |
| Publisher / Ed. Institution: | Washington |
| ISSN: | 0022-3654 1541-5740 |
| Language: | English |
| Subjects: | Fullerenes; Endohedral fullerene |
| Subject (DDC): | 540: Chemistry |
| Abstract: | The technique or carbon-arc evaporation has been successfully utilized to encapsulate a wide variet y of rare-earth species in carbon cases. We have observed Mm@Cn (M = Ce, Nd, Sm. Eu, Gd, Tb, Dy, Ho or Er } species present in the toluene extracts of the carbon soot using laser desorption mass spectrometry. The presence of multiple-metal species appears to depend strongly on the metal-to-carbon atom ratio found in the starting rods, with the higher metal concentrations favouring multiple-metal incorporation. One often observed dimetallcfullerene is M2@C80. Molecular orbital arguments are presented to support a possible icosahedral structure for C80. |
| URI: | https://digitalcollection.zhaw.ch/handle/11475/5444 |
| Fulltext version: | Published version |
| License (according to publishing contract): | Licence according to publishing contract |
| Departement: | Life Sciences and Facility Management |
| Organisational Unit: | Institute of Chemistry and Biotechnology (ICBT) |
| Appears in collections: | Publikationen Life Sciences und Facility Management |
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Gillan, E. G., Yeretzian, C., Min, K. S., Alvarez, M. M., Whetten, R. L., & Kaner, R. B. (1992). Endohedral rare-earth fullerene complexes. The Journal of Physical Chemistry, 96(17), 6869–6871. https://doi.org/10.1021/j100196a006
Gillan, E.G. et al. (1992) ‘Endohedral rare-earth fullerene complexes’, The Journal of Physical Chemistry, 96(17), pp. 6869–6871. Available at: https://doi.org/10.1021/j100196a006.
E. G. Gillan, C. Yeretzian, K. S. Min, M. M. Alvarez, R. L. Whetten, and R. B. Kaner, “Endohedral rare-earth fullerene complexes,” The Journal of Physical Chemistry, vol. 96, no. 17, pp. 6869–6871, Aug. 1992, doi: 10.1021/j100196a006.
GILLAN, Edward G., Chahan YERETZIAN, Kyu S. MIN, Marcos M. ALVAREZ, Robert L. WHETTEN und Richard B. KANER, 1992. Endohedral rare-earth fullerene complexes. The Journal of Physical Chemistry. August 1992. Bd. 96, Nr. 17, S. 6869–6871. DOI 10.1021/j100196a006
Gillan, Edward G., Chahan Yeretzian, Kyu S. Min, Marcos M. Alvarez, Robert L. Whetten, and Richard B. Kaner. 1992. “Endohedral Rare-Earth Fullerene Complexes.” The Journal of Physical Chemistry 96 (17): 6869–71. https://doi.org/10.1021/j100196a006.
Gillan, Edward G., et al. “Endohedral Rare-Earth Fullerene Complexes.” The Journal of Physical Chemistry, vol. 96, no. 17, Aug. 1992, pp. 6869–71, https://doi.org/10.1021/j100196a006.
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