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dc.contributor.authorHeiz, Ueli-
dc.contributor.authorVayloyan, Arthur-
dc.contributor.authorSchuhmacher, Ernst-
dc.contributor.authorYeretzian, Chahan-
dc.contributor.authorStener, Mauro-
dc.contributor.authorGisdakis, Philip-
dc.contributor.authorRösch, Notkter-
dc.date.accessioned2018-04-23T08:32:36Z-
dc.date.available2018-04-23T08:32:36Z-
dc.date.issued1996-06-
dc.identifier.issn0021-9606de_CH
dc.identifier.issn1089-7690de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/5443-
dc.description.abstractMixed metal clusters of sodium and cesium with gold have been generated in a supersonic expansion from the mixed vapor phase. Their tendency towards binary cluster formation, relative thermodynamic stability, and ionization potentials have been experimentally and computationally investigated. The properties of the NaxAu clusters may be understood within an electronic shell model based on delocalized cluster orbitals, whereas the characteristics of CsxAu are indicative of substantial ionic interactions. Relativistic density functional calculations have been performed to elucidate the cluster electronic structure and to rationalize observed properties which may not be accounted for by the jellium model. The properties of these finite-size clusters are shown to be related to the known bulk intermetallic compounds sodium gold and cesium-gold (cesium aurid), respectively.de_CH
dc.language.isoende_CH
dc.publisherAmerican Institute of Physicsde_CH
dc.relation.ispartofThe Journal of Chemical Physicsde_CH
dc.rightsLicence according to publishing contractde_CH
dc.subjectBimetalic clustersde_CH
dc.subjectAlkali clustersde_CH
dc.subjectClustersde_CH
dc.subject.ddc540: Chemiede_CH
dc.titleNaxAu and CsxAu bimetal clusters : finite size analogs of sodium-gold and caesium-gold compoundsde_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementLife Sciences und Facility Managementde_CH
zhaw.publisher.placeMelvillede_CH
dc.identifier.doi10.1063/1.472397de_CH
zhaw.funding.euNode_CH
zhaw.issue13de_CH
zhaw.originated.zhawYesde_CH
zhaw.pages.end5585de_CH
zhaw.pages.start5574de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume105de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
Appears in collections:Publikationen Life Sciences und Facility Management

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Heiz, U., Vayloyan, A., Schuhmacher, E., Yeretzian, C., Stener, M., Gisdakis, P., & Rösch, N. (1996). NaxAu and CsxAu bimetal clusters : finite size analogs of sodium-gold and caesium-gold compounds. The Journal of Chemical Physics, 105(13), 5574–5585. https://doi.org/10.1063/1.472397
Heiz, U. et al. (1996) ‘NaxAu and CsxAu bimetal clusters : finite size analogs of sodium-gold and caesium-gold compounds’, The Journal of Chemical Physics, 105(13), pp. 5574–5585. Available at: https://doi.org/10.1063/1.472397.
U. Heiz et al., “NaxAu and CsxAu bimetal clusters : finite size analogs of sodium-gold and caesium-gold compounds,” The Journal of Chemical Physics, vol. 105, no. 13, pp. 5574–5585, Jun. 1996, doi: 10.1063/1.472397.
HEIZ, Ueli, Arthur VAYLOYAN, Ernst SCHUHMACHER, Chahan YERETZIAN, Mauro STENER, Philip GISDAKIS und Notkter RÖSCH, 1996. NaxAu and CsxAu bimetal clusters : finite size analogs of sodium-gold and caesium-gold compounds. The Journal of Chemical Physics. Juni 1996. Bd. 105, Nr. 13, S. 5574–5585. DOI 10.1063/1.472397
Heiz, Ueli, Arthur Vayloyan, Ernst Schuhmacher, Chahan Yeretzian, Mauro Stener, Philip Gisdakis, and Notkter Rösch. 1996. “NaxAu and CsxAu Bimetal Clusters : Finite Size Analogs of Sodium-Gold and Caesium-Gold Compounds.” The Journal of Chemical Physics 105 (13): 5574–85. https://doi.org/10.1063/1.472397.
Heiz, Ueli, et al. “NaxAu and CsxAu Bimetal Clusters : Finite Size Analogs of Sodium-Gold and Caesium-Gold Compounds.” The Journal of Chemical Physics, vol. 105, no. 13, June 1996, pp. 5574–85, https://doi.org/10.1063/1.472397.


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