| Publication type: | Article in scientific journal |
| Type of review: | Peer review (publication) |
| Title: | Activated poly(hydromethylsiloxane)s as novel adhesion promoters for metallic surfaces |
| Authors: | Hirayama, Martina Soares, Marie Caseri, Walter Suter, Ulrich Goussev, Olga |
| DOI: | 10.1080/00218460008029267 |
| Published in: | Journal of Adhesion |
| Volume(Issue): | 72 |
| Issue: | 1 |
| Page(s): | 51 |
| Pages to: | 63 |
| Issue Date: | 2000 |
| Publisher / Ed. Institution: | Taylor & Francis |
| ISSN: | 1545-5823 |
| Language: | English |
| Subjects: | Coating; Siloxane; Polymer; Adhesion promotion |
| Subject (DDC): | 540: Chemistry |
| Abstract: | A poly(hydromethylsiloxane) (PHMS) was bound to aluminium, copper, and steel surfaces via activation with cis-[PtCl2(PhCH=CH2)2] in solution at room temperature. The attached polymer promotes the adhesion to two-component silicone resins where the curing process is based on catalytic hydrosilylation of olefines. In lap-shear or peel tests, cohesive failure was always observed. An example shows that the adhesive joint withstood boiling water for 200 h without considerable loss of adhesive strength. It is suggested that a small fraction of the olefinic component of the resin, e.g., a poly(dimethylsiloxane) containing some olefinic groups, is also connected with the attached PHMS via catalytic hydrosilylation, thus binding the silicone resin to the surface via the PHMS layer. |
| URI: | https://digitalcollection.zhaw.ch/handle/11475/3032 |
| Fulltext version: | Published version |
| License (according to publishing contract): | Licence according to publishing contract |
| Departement: | School of Engineering |
| Appears in collections: | Publikationen School of Engineering |
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Hirayama, M., Soares, M., Caseri, W., Suter, U., & Goussev, O. (2000). Activated poly(hydromethylsiloxane)s as novel adhesion promoters for metallic surfaces. Journal of Adhesion, 72(1), 51–63. https://doi.org/10.1080/00218460008029267
Hirayama, M. et al. (2000) ‘Activated poly(hydromethylsiloxane)s as novel adhesion promoters for metallic surfaces’, Journal of Adhesion, 72(1), pp. 51–63. Available at: https://doi.org/10.1080/00218460008029267.
M. Hirayama, M. Soares, W. Caseri, U. Suter, and O. Goussev, “Activated poly(hydromethylsiloxane)s as novel adhesion promoters for metallic surfaces,” Journal of Adhesion, vol. 72, no. 1, pp. 51–63, 2000, doi: 10.1080/00218460008029267.
HIRAYAMA, Martina, Marie SOARES, Walter CASERI, Ulrich SUTER und Olga GOUSSEV, 2000. Activated poly(hydromethylsiloxane)s as novel adhesion promoters for metallic surfaces. Journal of Adhesion. 2000. Bd. 72, Nr. 1, S. 51–63. DOI 10.1080/00218460008029267
Hirayama, Martina, Marie Soares, Walter Caseri, Ulrich Suter, and Olga Goussev. 2000. “Activated Poly(hydromethylsiloxane)s as Novel Adhesion Promoters for Metallic Surfaces.” Journal of Adhesion 72 (1): 51–63. https://doi.org/10.1080/00218460008029267.
Hirayama, Martina, et al. “Activated Poly(hydromethylsiloxane)s as Novel Adhesion Promoters for Metallic Surfaces.” Journal of Adhesion, vol. 72, no. 1, 2000, pp. 51–63, https://doi.org/10.1080/00218460008029267.
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