Title: Direct synthesis and fluorescent imaging of bifunctionalized mesoporous iodopropyl-silica
Authors : Ramm, Jan Hinrich
Gartmann, Nando
Brühwiler, Dominik
Published in : Journal of Colloid and Interface Science
Volume(Issue) : 345
Issue : 2
Pages : 200
Pages to: 205
Publisher / Ed. Institution : Academic Press
Issue Date: 2010
License (according to publishing contract) : Licence according to publishing contract
Type of review: Peer review (Publication)
Language : English
Subjects : ICBC; Mesopores; Iodopropyl
Subject (DDC) : 540: Chemistry
Abstract: The cocondensation of 3-iodopropyltrimethoxysilane and tetraethoxysilane with an additional substituted trimethoxysilane (RTMS) in the presence of Pluronic P123 and hydrogen iodide yields bifunctionalized mesoporous silica. The pore-size distribution of these materials depends on the nature of the RTMS additive. Excellent results in terms of a narrow pore-size distribution were obtained with methyltrimethoxysilane. A particularly interesting bifunctionalized mesoporous material is formed by the coinclusion of iodopropyl and aminopropyl moieties. The complementary reactivity of these two functional groups is demonstrated by the selective labeling of the amino-iodo-functionalized mesoporous silica with 2-hydroxy-substituted Nile red and fluorescein isothiocyanate, allowing further characterization of the functional group distribution by confocal laser scanning microscopy.
Departement: Life Sciences und Facility Management
Organisational Unit: Institute of Chemistry and Biotechnology (ICBT)
Publication type: Article in scientific Journal
DOI : 10.1016/j.jcis.2010.01.070
10.5167/uzh-33745
ISSN: 0021-9797
URI: https://digitalcollection.zhaw.ch/handle/11475/2663
Appears in Collections:Publikationen Life Sciences und Facility Management

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