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dc.contributor.authorPrestat, Michel-
dc.contributor.authorMorandi, A.-
dc.contributor.authorHeel, Andre-
dc.contributor.authorHolzer, Lorenz-
dc.contributor.authorHoltappels, Peter-
dc.contributor.authorGraule, Thomas J.-
dc.date.accessioned2018-01-25T10:50:14Z-
dc.date.available2018-01-25T10:50:14Z-
dc.date.issued2010-
dc.identifier.issn1388-2481de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/2196-
dc.description.abstractThis study aimed at fabricating porous crack-free and delamination-free La0.6Sr0.4CoO3−δ electrodes using nanopowders and investigating oxygen reduction (occurring at solid oxide fuel cell cathodes) and oxygen evolution (occurring at solid oxide electrolysis cell anodes) at 600°C in air. The electrodes were deposited by screen-printing on Ce0.8Gd0.2O1.9 substrates. The pastes were prepared with nanoparticles synthesised by flame spray synthesis and graphite pore former. Without graphite, the electrodes sintered at 100°C exhibit relatively low porosity and significant densification which led to partial delamination and large overpotentials. The addition of graphite, which was removed by combustion at ca. 650°C during sintering, markedly improves electrode performance by increasing porosity and reducing densification. A minimal overpotential for both the oxygen reduction and oxygen evolution was reached for a layer porosity of ca. 50-60 vol.%.de_CH
dc.language.isoende_CH
dc.publisherElsevierde_CH
dc.relation.ispartofElectrochemistry Communicationsde_CH
dc.rightsLicence according to publishing contractde_CH
dc.subjectMapde_CH
dc.subject.ddc540: Chemiede_CH
dc.subject.ddc620.11: Werkstoffede_CH
dc.titleEffect of graphite pore former on oxygen electrodes prepared with La0.6Sr0.4CoO3−δ nanoparticlesde_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementSchool of Engineeringde_CH
zhaw.organisationalunitInstitute of Computational Physics (ICP)de_CH
zhaw.organisationalunitInstitute of Materials and Process Engineering (IMPE)de_CH
dc.identifier.doi10.1016/j.elecom.2009.12.018de_CH
zhaw.funding.euNode_CH
zhaw.issue2de_CH
zhaw.originated.zhawYesde_CH
zhaw.pages.end295de_CH
zhaw.pages.start292de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume12de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
Appears in collections:Publikationen School of Engineering

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Prestat, M., Morandi, A., Heel, A., Holzer, L., Holtappels, P., & Graule, T. J. (2010). Effect of graphite pore former on oxygen electrodes prepared with La0.6Sr0.4CoO3−δ nanoparticles. Electrochemistry Communications, 12(2), 292–295. https://doi.org/10.1016/j.elecom.2009.12.018
Prestat, M. et al. (2010) ‘Effect of graphite pore former on oxygen electrodes prepared with La0.6Sr0.4CoO3−δ nanoparticles’, Electrochemistry Communications, 12(2), pp. 292–295. Available at: https://doi.org/10.1016/j.elecom.2009.12.018.
M. Prestat, A. Morandi, A. Heel, L. Holzer, P. Holtappels, and T. J. Graule, “Effect of graphite pore former on oxygen electrodes prepared with La0.6Sr0.4CoO3−δ nanoparticles,” Electrochemistry Communications, vol. 12, no. 2, pp. 292–295, 2010, doi: 10.1016/j.elecom.2009.12.018.
PRESTAT, Michel, A. MORANDI, Andre HEEL, Lorenz HOLZER, Peter HOLTAPPELS und Thomas J. GRAULE, 2010. Effect of graphite pore former on oxygen electrodes prepared with La0.6Sr0.4CoO3−δ nanoparticles. Electrochemistry Communications. 2010. Bd. 12, Nr. 2, S. 292–295. DOI 10.1016/j.elecom.2009.12.018
Prestat, Michel, A. Morandi, Andre Heel, Lorenz Holzer, Peter Holtappels, and Thomas J. Graule. 2010. “Effect of Graphite Pore Former on Oxygen Electrodes Prepared with La0.6Sr0.4CoO3−δ Nanoparticles.” Electrochemistry Communications 12 (2): 292–95. https://doi.org/10.1016/j.elecom.2009.12.018.
Prestat, Michel, et al. “Effect of Graphite Pore Former on Oxygen Electrodes Prepared with La0.6Sr0.4CoO3−δ Nanoparticles.” Electrochemistry Communications, vol. 12, no. 2, 2010, pp. 292–95, https://doi.org/10.1016/j.elecom.2009.12.018.


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