Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Prestat, Michel | - |
dc.contributor.author | Morandi, A. | - |
dc.contributor.author | Heel, Andre | - |
dc.contributor.author | Holzer, Lorenz | - |
dc.contributor.author | Holtappels, Peter | - |
dc.contributor.author | Graule, Thomas J. | - |
dc.date.accessioned | 2018-01-25T10:50:14Z | - |
dc.date.available | 2018-01-25T10:50:14Z | - |
dc.date.issued | 2010 | - |
dc.identifier.issn | 1388-2481 | de_CH |
dc.identifier.uri | https://digitalcollection.zhaw.ch/handle/11475/2196 | - |
dc.description.abstract | This study aimed at fabricating porous crack-free and delamination-free La0.6Sr0.4CoO3−δ electrodes using nanopowders and investigating oxygen reduction (occurring at solid oxide fuel cell cathodes) and oxygen evolution (occurring at solid oxide electrolysis cell anodes) at 600°C in air. The electrodes were deposited by screen-printing on Ce0.8Gd0.2O1.9 substrates. The pastes were prepared with nanoparticles synthesised by flame spray synthesis and graphite pore former. Without graphite, the electrodes sintered at 100°C exhibit relatively low porosity and significant densification which led to partial delamination and large overpotentials. The addition of graphite, which was removed by combustion at ca. 650°C during sintering, markedly improves electrode performance by increasing porosity and reducing densification. A minimal overpotential for both the oxygen reduction and oxygen evolution was reached for a layer porosity of ca. 50-60 vol.%. | de_CH |
dc.language.iso | en | de_CH |
dc.publisher | Elsevier | de_CH |
dc.relation.ispartof | Electrochemistry Communications | de_CH |
dc.rights | Licence according to publishing contract | de_CH |
dc.subject | Map | de_CH |
dc.subject.ddc | 540: Chemie | de_CH |
dc.subject.ddc | 620.11: Werkstoffe | de_CH |
dc.title | Effect of graphite pore former on oxygen electrodes prepared with La0.6Sr0.4CoO3−δ nanoparticles | de_CH |
dc.type | Beitrag in wissenschaftlicher Zeitschrift | de_CH |
dcterms.type | Text | de_CH |
zhaw.departement | School of Engineering | de_CH |
zhaw.organisationalunit | Institute of Computational Physics (ICP) | de_CH |
zhaw.organisationalunit | Institute of Materials and Process Engineering (IMPE) | de_CH |
dc.identifier.doi | 10.1016/j.elecom.2009.12.018 | de_CH |
zhaw.funding.eu | No | de_CH |
zhaw.issue | 2 | de_CH |
zhaw.originated.zhaw | Yes | de_CH |
zhaw.pages.end | 295 | de_CH |
zhaw.pages.start | 292 | de_CH |
zhaw.publication.status | publishedVersion | de_CH |
zhaw.volume | 12 | de_CH |
zhaw.publication.review | Peer review (Publikation) | de_CH |
Appears in collections: | Publikationen School of Engineering |
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Prestat, M., Morandi, A., Heel, A., Holzer, L., Holtappels, P., & Graule, T. J. (2010). Effect of graphite pore former on oxygen electrodes prepared with La0.6Sr0.4CoO3−δ nanoparticles. Electrochemistry Communications, 12(2), 292–295. https://doi.org/10.1016/j.elecom.2009.12.018
Prestat, M. et al. (2010) ‘Effect of graphite pore former on oxygen electrodes prepared with La0.6Sr0.4CoO3−δ nanoparticles’, Electrochemistry Communications, 12(2), pp. 292–295. Available at: https://doi.org/10.1016/j.elecom.2009.12.018.
M. Prestat, A. Morandi, A. Heel, L. Holzer, P. Holtappels, and T. J. Graule, “Effect of graphite pore former on oxygen electrodes prepared with La0.6Sr0.4CoO3−δ nanoparticles,” Electrochemistry Communications, vol. 12, no. 2, pp. 292–295, 2010, doi: 10.1016/j.elecom.2009.12.018.
PRESTAT, Michel, A. MORANDI, Andre HEEL, Lorenz HOLZER, Peter HOLTAPPELS und Thomas J. GRAULE, 2010. Effect of graphite pore former on oxygen electrodes prepared with La0.6Sr0.4CoO3−δ nanoparticles. Electrochemistry Communications. 2010. Bd. 12, Nr. 2, S. 292–295. DOI 10.1016/j.elecom.2009.12.018
Prestat, Michel, A. Morandi, Andre Heel, Lorenz Holzer, Peter Holtappels, and Thomas J. Graule. 2010. “Effect of Graphite Pore Former on Oxygen Electrodes Prepared with La0.6Sr0.4CoO3−δ Nanoparticles.” Electrochemistry Communications 12 (2): 292–95. https://doi.org/10.1016/j.elecom.2009.12.018.
Prestat, Michel, et al. “Effect of Graphite Pore Former on Oxygen Electrodes Prepared with La0.6Sr0.4CoO3−δ Nanoparticles.” Electrochemistry Communications, vol. 12, no. 2, 2010, pp. 292–95, https://doi.org/10.1016/j.elecom.2009.12.018.
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