Comparing Grubbs-, Werner-, and Hofmann-type (carbene)ruthenium complexes : the key role of pre-equilibria for olefin metathesis

Adlhart, Christian; Volland, Martin A. O.; Hofmann, Peter; Chen, Peter

doi:10.1002/1522-2675(20001220)83:12<3306::AID-HLCA3306>3.0.CO;2-7

Publication type:	Article in scientific journal
Type of review:	Peer review (publication)
Title:	Comparing Grubbs-, Werner-, and Hofmann-type (carbene)ruthenium complexes : the key role of pre-equilibria for olefin metathesis
Authors:	Adlhart, Christian Volland, Martin A. O. Hofmann, Peter Chen, Peter
DOI:	10.1002/1522-2675(20001220)83:12<3306::AID-HLCA3306>3.0.CO;2-7
Published in:	Helvetica Chimica Acta
Volume(Issue):	83
Issue:	12
Page(s):	3306
Pages to:	3311
Issue Date:	20-Dec-2000
Publisher / Ed. Institution:	Wiley
Publisher / Ed. Institution:	Hoboken
ISSN:	0018-019X 1522-2675
Language:	English
Subjects:	Metathesis kinetics; Reaction mechanism; Electrospray ionization mass spectrometry; Equilibrium
Subject (DDC):	540: Chemistry
Abstract:	A gas-phase comparison of intrinsic olefin metathesis rates for (carbene)ruthenium complexes by means of electrospray-ionization tandem mass spectrometry reveals a reversal of the reactivity trends observed in solution. The solution-phase ordering of reactivity is accordingly attributed to a more favorable pre-equilibrium, producing the metathesis-active species in the case of the Hofmann- and Werner-type complexes relative to those of the Grubbs type.
URI:	https://digitalcollection.zhaw.ch/handle/11475/2090
Fulltext version:	Published version
License (according to publishing contract):	Licence according to publishing contract
Departement:	Life Sciences and Facility Management
Organisational Unit:	Institute of Chemistry and Biotechnology (ICBT)
Appears in collections:	Publikationen Life Sciences und Facility Management

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Adlhart, C., Volland, M. A. O., Hofmann, P., & Chen, P. (2000). Comparing Grubbs-, Werner-, and Hofmann-type (carbene)ruthenium complexes : the key role of pre-equilibria for olefin metathesis. Helvetica Chimica Acta, 83(12), 3306–3311. https://doi.org/10.1002/1522-2675(20001220)83:12<3306::AID-HLCA3306>3.0.CO;2-7

Adlhart, C. et al. (2000) ‘Comparing Grubbs-, Werner-, and Hofmann-type (carbene)ruthenium complexes : the key role of pre-equilibria for olefin metathesis’, Helvetica Chimica Acta, 83(12), pp. 3306–3311. Available at: https://doi.org/10.1002/1522-2675(20001220)83:12<3306::AID-HLCA3306>3.0.CO;2-7.

C. Adlhart, M. A. O. Volland, P. Hofmann, and P. Chen, “Comparing Grubbs-, Werner-, and Hofmann-type (carbene)ruthenium complexes : the key role of pre-equilibria for olefin metathesis,” Helvetica Chimica Acta, vol. 83, no. 12, pp. 3306–3311, Dec. 2000, doi: 10.1002/1522-2675(20001220)83:12<3306::AID-HLCA3306>3.0.CO;2-7.

ADLHART, Christian, Martin A. O. VOLLAND, Peter HOFMANN und Peter CHEN, 2000. Comparing Grubbs-, Werner-, and Hofmann-type (carbene)ruthenium complexes : the key role of pre-equilibria for olefin metathesis. Helvetica Chimica Acta. 20 Dezember 2000. Bd. 83, Nr. 12, S. 3306–3311. DOI 10.1002/1522-2675(20001220)83:12<3306::AID-HLCA3306>3.0.CO;2-7

Adlhart, Christian, Martin A. O. Volland, Peter Hofmann, and Peter Chen. 2000. “Comparing Grubbs-, Werner-, and Hofmann-Type (Carbene)ruthenium Complexes : The Key Role of Pre-Equilibria for Olefin Metathesis.” Helvetica Chimica Acta 83 (12): 3306–11. https://doi.org/10.1002/1522-2675(20001220)83:12<3306::AID-HLCA3306>3.0.CO;2-7.

Adlhart, Christian, et al. “Comparing Grubbs-, Werner-, and Hofmann-Type (Carbene)ruthenium Complexes : The Key Role of Pre-Equilibria for Olefin Metathesis.” Helvetica Chimica Acta, vol. 83, no. 12, Dec. 2000, pp. 3306–11, https://doi.org/10.1002/1522-2675(20001220)83:12<3306::AID-HLCA3306>3.0.CO;2-7.