Publication type: Article in scientific journal
Type of review: Peer review (publication)
Title: Fishing for catalysts : mechanism-based probes for active species in solution
Authors: Adlhart, Christian
Chen, Peter
DOI: 10.1002/1522-2675(20000906)83:9<2192::AID-HLCA2192>3.0.CO;2-G
Published in: Helvetica Chimica Acta
Volume(Issue): 83
Issue: 9
Pages: 2192
Pages to: 2196
Issue Date: 6-Sep-2000
Publisher / Ed. Institution: Wiley
Publisher / Ed. Institution: Hoboken
ISSN: 0018-019X
Language: English
Subjects: Polymerization catalysts; Polyalkenamers; Electrospray ionization mass spectrometry; Catalytically active species
Subject (DDC): 660: Chemical engineering
Abstract: A combination of derivatization with charged substrates and electrospray-ionization mass spectrometry was used to det. the active species in a polymn. reaction. The obsd. species by mass spectrometry corresponds to the resting state of the catalyst. Data for the ring-opening metathesis polymn. (ROMP) of norbornene using (Cy3P)2Cl2Ru=CHPh (Cy = cyclohexyl) was used to illustrate the method.
Fulltext version: Published version
License (according to publishing contract): Licence according to publishing contract
Departement: Life Sciences and Facility Management
Organisational Unit: Institute of Chemistry and Biotechnology (ICBT)
Appears in Collections:Publikationen Life Sciences und Facility Management

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