Title: Fishing for catalysts : mechanism-based probes for active species in solution
Authors : Adlhart, Christian
Chen, Peter
Published in : Helvetica Chimica Acta
Volume(Issue) : 83
Issue : 9
Pages : 2192
Pages to: 2196
Publisher / Ed. Institution : Wiley
Publisher / Ed. Institution: Hoboken, New Jersey
Issue Date: 6-Sep-2000
License (according to publishing contract) : Licence according to publishing contract
Type of review: Peer review (Publication)
Language : English
Subjects : Polymerization catalysts; Polyalkenamers; Electrospray ionization mass spectrometry; Catalytically active species
Subject (DDC) : 660: Chemical engineering
Abstract: A combination of derivatization with charged substrates and electrospray-ionization mass spectrometry was used to det. the active species in a polymn. reaction. The obsd. species by mass spectrometry corresponds to the resting state of the catalyst. Data for the ring-opening metathesis polymn. (ROMP) of norbornene using (Cy3P)2Cl2Ru=CHPh (Cy = cyclohexyl) was used to illustrate the method.
Departement: Life Sciences und Facility Management
Organisational Unit: Institute of Chemistry and Biotechnology (ICBT)
Publication type: Article in scientific Journal
DOI : 10.1002/1522-2675(20000906)83:9<2192::AID-HLCA2192>3.0.CO;2-G
ISSN: 0018-019X
URI: https://digitalcollection.zhaw.ch/handle/11475/2089
Appears in Collections:Publikationen Life Sciences und Facility Management

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