| Publication type: | Article in scientific journal |
| Type of review: | Peer review (publication) |
| Title: | Mechanisms of catalytic dehydrogenation of alkanes by rhodium clusters Rhn+ probed by isotope labelling |
| Authors: | Adlhart, Christian Uggerud, Einar |
| DOI: | 10.1016/j.ijms.2005.12.032 |
| Published in: | International Journal of Mass Spectrometry |
| Volume(Issue): | 249-250 |
| Page(s): | 191 |
| Pages to: | 198 |
| Issue Date: | 20-Jan-2006 |
| Publisher / Ed. Institution: | Elsevier |
| Publisher / Ed. Institution: | Amsterdam |
| ISSN: | 1387-3806 1873-2798 |
| Language: | English |
| Subjects: | Metal cluster; Ion molecule reaction; Deuterium labelling; Nanotechnology |
| Subject (DDC): | 540: Chemistry |
| Abstract: | The regioselectivity for the dehydrogenation of alkanes by rhodium clusters was investigated by reacting Rhn+, n = 1-20, with the isotopically labelled alkanes ethane-1,1,1-d3 and propane-1,1,1,3,3,3-d6. For Rh+ reacting with propane a clear preference for a 1,2- over a 1,1- and 1,3-mechanism was observed. For larger clusters, hydrogen scrambling is faster than hydrogen elimination, which essentially leads to statistical formation of the neutrals H2, HD, and D2. Isotope scrambling with D2 was also used as a structural probe for the reaction products of rhodium clusters with ethane. The intactness of the CH bonds was demonstrated for (n > 6). The studies are completed with a detailed kinetic analysis for the reaction of Rh7+ with ethane and ethane/hydrogen and ethane/helium mixtures. An over-all picture with efficient CH bond activation and fast and reversible hydrogen rearrangements emerges on the basis of these experiments. Some of the dehydrogenation reactions appear to be reversible. |
| URI: | https://digitalcollection.zhaw.ch/handle/11475/2065 |
| Fulltext version: | Published version |
| License (according to publishing contract): | Licence according to publishing contract |
| Departement: | Life Sciences and Facility Management |
| Organisational Unit: | Institute of Chemistry and Biotechnology (ICBT) |
| Appears in collections: | Publikationen Life Sciences und Facility Management |
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Adlhart, C., & Uggerud, E. (2006). Mechanisms of catalytic dehydrogenation of alkanes by rhodium clusters Rhn+ probed by isotope labelling. International Journal of Mass Spectrometry, 249-250, 191–198. https://doi.org/10.1016/j.ijms.2005.12.032
Adlhart, C. and Uggerud, E. (2006) ‘Mechanisms of catalytic dehydrogenation of alkanes by rhodium clusters Rhn+ probed by isotope labelling’, International Journal of Mass Spectrometry, 249-250, pp. 191–198. Available at: https://doi.org/10.1016/j.ijms.2005.12.032.
C. Adlhart and E. Uggerud, “Mechanisms of catalytic dehydrogenation of alkanes by rhodium clusters Rhn+ probed by isotope labelling,” International Journal of Mass Spectrometry, vol. 249-250, pp. 191–198, Jan. 2006, doi: 10.1016/j.ijms.2005.12.032.
ADLHART, Christian und Einar UGGERUD, 2006. Mechanisms of catalytic dehydrogenation of alkanes by rhodium clusters Rhn+ probed by isotope labelling. International Journal of Mass Spectrometry. 20 Januar 2006. Bd. 249-250, S. 191–198. DOI 10.1016/j.ijms.2005.12.032
Adlhart, Christian, and Einar Uggerud. 2006. “Mechanisms of Catalytic Dehydrogenation of Alkanes by Rhodium Clusters Rhn+ Probed by Isotope Labelling.” International Journal of Mass Spectrometry 249-250 (January): 191–98. https://doi.org/10.1016/j.ijms.2005.12.032.
Adlhart, Christian, and Einar Uggerud. “Mechanisms of Catalytic Dehydrogenation of Alkanes by Rhodium Clusters Rhn+ Probed by Isotope Labelling.” International Journal of Mass Spectrometry, vol. 249-250, Jan. 2006, pp. 191–98, https://doi.org/10.1016/j.ijms.2005.12.032.
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