Please use this identifier to cite or link to this item: https://doi.org/10.21256/zhaw-3458
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dc.contributor.authorZucchetto, Nicola-
dc.contributor.authorReber, Michael-
dc.contributor.authorPestalozzi, Lias-
dc.contributor.authorSchmid, Ramon-
dc.contributor.authorNeels, Antonia-
dc.contributor.authorBrühwiler, Dominik-
dc.date.accessioned2017-11-20T13:06:35Z-
dc.date.available2017-11-20T13:06:35Z-
dc.date.issued2018-
dc.identifier.issn1387-1811de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/1513-
dc.description.abstractMesoporous silica with bimodal pore size distributions was prepared by pseudomorphic transformation of SBA-15 and SBA-16 in the presence of hexadecyltrimethylammonium ions as a structure-directing agent. The characteristic particle morphology of the starting materials was retained after the transformation. Analysis of the products by gas sorption and small-angle X-ray scattering (SAXS) revealed hybrid pore structures, which featured – depending on the degree of transformation – variable contributions from the original and the newly introduced pore systems. In the case of SBA-15, it was found that a high degree of transformation leads to a seemingly complete conversion of the original pores with a diameter of 7.1 nm to pores with a diameter of 4.0 nm. The SAXS pattern of the product shows additional peaks that can be assigned to the original SBA-15 pore spacing. Similarly, a cubic phase could be observed in the samples prepared by pseudomorphic transformation of SBA-16, despite an almost complete conversion of the SBA-16 cavities. This leads to the conclusion that the pore structure of the starting material significantly affects the outcome of the pseudomorphic transformation, thus opening possibilities for the synthesis of new porous materials with complex pore systems.de_CH
dc.language.isoende_CH
dc.publisherElsevierde_CH
dc.relation.ispartofMicroporous and Mesoporous Materialsde_CH
dc.rightsLicence according to publishing contractde_CH
dc.subjectBimodal mesoporous silicade_CH
dc.subjectHybrid pore structurede_CH
dc.subjectPseudomorphic transformationde_CH
dc.subjectCavitation; Bottleneckde_CH
dc.subject.ddc540: Chemiede_CH
dc.titleThe structure of mesoporous silica obtained by pseudomorphic transformation of SBA-15 and SBA-16de_CH
dc.typeTextde_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
zhaw.departementLife Sciences und Facility Managementde_CH
zhaw.organisationalunitInstitut für Chemie und Biotechnologie (ICBT)de_CH
dc.identifier.doi10.1016/j.micromeso.2017.08.046de_CH
dc.identifier.doi10.21256/zhaw-3458de_CH
zhaw.funding.euNode_CH
zhaw.originated.zhawYesde_CH
zhaw.pages.end240de_CH
zhaw.pages.start232de_CH
zhaw.publication.statusacceptedVersionde_CH
zhaw.volume257de_CH
zhaw.embargo.end17.11.2019-
zhaw.publication.reviewPeer review (Publikation)de_CH
zhaw.funding.snf200021_172805de_CH
zhaw.monitoring.oajournalNot specifiedde_CH
Appears in Collections:Publikationen Life Sciences und Facility Management

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