Title: Stochastic modelling of ion diffusion in complex systems
Authors : Dieterich, Wolfgang
Dürr, Oliver
Pendzig, Peter
Nitzan, Abraham
Published in : Anomalous Diffusion From Basics to Applications
Pages : 175
Pages to: 185
Conference details: XIth Max Born Symposium, Lądek Zdrój, Poland, 20-27 May 1998
Publisher / Ed. Institution : Springer
Publisher / Ed. Institution: Berlin
Issue Date: 1999
License (according to publishing contract) : Licence according to publishing contract
Series : Lecture Notes in Physics
Series volume: 519
Type of review: Editorial review
Language : English
Subject (DDC) : 530: Physics
Abstract: Fast ion conduction is known to occur in many solid materials, allowing us to perform fundamental studies of diffusion processes in a variety of structures. After briefly discussing classes of solid ionic conductors with increasing complexity in their structural and transport behaviour, we shall focus on polymer electrolytes. A lattice model is described which emphasizes the asymmetry in the cation-polymer and anion-polymer interactions. Monte-Carlo simulations of the equation of state are supplemented by calculations based on the quasi-chemical approximation. Simulated diffusion constants and their dependence on temperature and ion concentration are compared with recent experiments on PEO (polyethylene oxid)-type conductors.
Departement: School of Engineering
Organisational Unit: Institute of Data Analysis and Process Design (IDP)
Publication type: Conference paper
DOI : 10.1007/BFb0106841
ISBN: 978-3-540-65416-2
978-3-540-49259-7
URI: https://digitalcollection.zhaw.ch/handle/11475/13864
Appears in Collections:Publikationen School of Engineering

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