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dc.contributor.authorHonciuc, Andrei-
dc.contributor.authorOtsuka, Akihiro-
dc.contributor.authorWang, Yu-Hsiang-
dc.contributor.authorMcElwee, Samuel K.-
dc.contributor.authorWoski, Stephen A.-
dc.contributor.authorSaito, Gunzi-
dc.contributor.authorMetzger, Robert M.-
dc.date.accessioned2018-12-12T07:44:51Z-
dc.date.available2018-12-12T07:44:51Z-
dc.date.issued2006-
dc.identifier.issn1520-6106de_CH
dc.identifier.issn1520-5207de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/13763-
dc.description.abstractA Langmuir-Blodgett (LB) multilayer film of the unimolecular rectifier hexadecyl-gamma-quinolinium-7,7,8-tricyanoquinodimethanide (C(16)H(33)gammaQ-3CNQ) has two distinct polarized charge-transfer bands, one at lower film pressures (28 mN m(-1)) with a peak at 530 nm, due to an intramolecular charge transfer or intervalence transfer (IVT); past the collapse point (32 to 35 mN m(-1)), this band disappears, and a new intermolecular charge-transfer band appears with peak at 570 nm. An LB multilayer film of the tetrafluoro analogue, hexadecyl-gamma-quinolinium-2,3,5,6-tetrafluoro-7,7,8-tricyanoquinodimethanide (C(16)H(33)gammaQ-3CNQF(4)) shows, for all film pressures, only one IVT band with a peak at 504 nm; when sandwiched between gold electrodes, (C(16)H(33)gammaQ-3CNQF(4) is also an LB monolayer electrical rectifier.de_CH
dc.language.isoende_CH
dc.publisherAmerican Chemical Societyde_CH
dc.relation.ispartofThe Journal of Physical Chemistry Bde_CH
dc.rightsLicence according to publishing contractde_CH
dc.subjectElectrodesde_CH
dc.subjectGoldde_CH
dc.subjectMolecular structurede_CH
dc.subjectNitrilesde_CH
dc.subjectQuinolinesde_CH
dc.subjectArtificial membranesde_CH
dc.subject.ddc540: Chemiede_CH
dc.titlePolarization of charge-transfer bands and rectification in hexadecylquinolinium 7,7,8-tricyanoquinodimethanide and its tetrafluoro analogde_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementLife Sciences und Facility Managementde_CH
dc.identifier.doi10.1021/jp056910qde_CH
dc.identifier.pmid16884220de_CH
zhaw.funding.euNode_CH
zhaw.issue31de_CH
zhaw.originated.zhawNode_CH
zhaw.pages.end15093de_CH
zhaw.pages.start15085de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume110de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
Appears in collections:Publikationen Life Sciences und Facility Management

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Honciuc, A., Otsuka, A., Wang, Y.-H., McElwee, S. K., Woski, S. A., Saito, G., & Metzger, R. M. (2006). Polarization of charge-transfer bands and rectification in hexadecylquinolinium 7,7,8-tricyanoquinodimethanide and its tetrafluoro analog. The Journal of Physical Chemistry B, 110(31), 15085–15093. https://doi.org/10.1021/jp056910q
Honciuc, A. et al. (2006) ‘Polarization of charge-transfer bands and rectification in hexadecylquinolinium 7,7,8-tricyanoquinodimethanide and its tetrafluoro analog’, The Journal of Physical Chemistry B, 110(31), pp. 15085–15093. Available at: https://doi.org/10.1021/jp056910q.
A. Honciuc et al., “Polarization of charge-transfer bands and rectification in hexadecylquinolinium 7,7,8-tricyanoquinodimethanide and its tetrafluoro analog,” The Journal of Physical Chemistry B, vol. 110, no. 31, pp. 15085–15093, 2006, doi: 10.1021/jp056910q.
HONCIUC, Andrei, Akihiro OTSUKA, Yu-Hsiang WANG, Samuel K. MCELWEE, Stephen A. WOSKI, Gunzi SAITO und Robert M. METZGER, 2006. Polarization of charge-transfer bands and rectification in hexadecylquinolinium 7,7,8-tricyanoquinodimethanide and its tetrafluoro analog. The Journal of Physical Chemistry B. 2006. Bd. 110, Nr. 31, S. 15085–15093. DOI 10.1021/jp056910q
Honciuc, Andrei, Akihiro Otsuka, Yu-Hsiang Wang, Samuel K. McElwee, Stephen A. Woski, Gunzi Saito, and Robert M. Metzger. 2006. “Polarization of Charge-Transfer Bands and Rectification in Hexadecylquinolinium 7,7,8-Tricyanoquinodimethanide and Its Tetrafluoro Analog.” The Journal of Physical Chemistry B 110 (31): 15085–93. https://doi.org/10.1021/jp056910q.
Honciuc, Andrei, et al. “Polarization of Charge-Transfer Bands and Rectification in Hexadecylquinolinium 7,7,8-Tricyanoquinodimethanide and Its Tetrafluoro Analog.” The Journal of Physical Chemistry B, vol. 110, no. 31, 2006, pp. 15085–93, https://doi.org/10.1021/jp056910q.


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