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dc.contributor.authorHinderling, Christian-
dc.contributor.authorFeichtinger, Derek-
dc.contributor.authorPlattner, Dietmar A.-
dc.contributor.authorChen, Peter-
dc.date.accessioned2018-12-11T15:43:27Z-
dc.date.available2018-12-11T15:43:27Z-
dc.date.issued1997-
dc.identifier.issn0002-7863de_CH
dc.identifier.issn1520-5126de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/13740-
dc.description.abstractA combination of electrospray ionization MS/MS techniques, isotopic labeling experiments in the gas-phase and solution, and ab initio calculations is used to study the C−H activation reactions of [Cp*Ir(PMe3)(CH3)]+ and [CpIr(PMe3)(CH3)]+. The reaction in the gas phase was found to proceed through a Cp or [Cp*Ir(η2-CH2PMe2)]+ intermediate. Quantitative collision-induced dissociation (CID) threshold measurements were used along with general models for ion−molecule reactions to construct potential energy diagrams which rationalize the gas-phase results. The comparison between the two complexes, and between the reactions in the gas phase and in solution, suggests that the reaction through the intermediacy of a metallaphosphacyclopropane could be favored over the conventional (and simpler) oxidative addition/reductive elimination mechanism when the Ir(III) complex is rendered more electron deficient.de_CH
dc.language.isoende_CH
dc.publisherAmerican Chemical Societyde_CH
dc.relation.ispartofJournal of the American Chemical Societyde_CH
dc.rightsLicence according to publishing contractde_CH
dc.subjectC-H activationde_CH
dc.subjectMechanismde_CH
dc.subjectIridiumde_CH
dc.subject.ddc540: Chemiede_CH
dc.titleA combined gas-phase, solution-phase, and computational study of C−H activation by cationic iridium(III) complexesde_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementLife Sciences und Facility Managementde_CH
zhaw.organisationalunitInstitut für Chemie und Biotechnologie (ICBT)de_CH
dc.identifier.doi10.1021/ja970995ude_CH
zhaw.funding.euNode_CH
zhaw.issue44de_CH
zhaw.originated.zhawNode_CH
zhaw.pages.end10804de_CH
zhaw.pages.start10793de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume119de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
Appears in collections:Publikationen Life Sciences und Facility Management

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Hinderling, C., Feichtinger, D., Plattner, D. A., & Chen, P. (1997). A combined gas-phase, solution-phase, and computational study of C−H activation by cationic iridium(III) complexes. Journal of the American Chemical Society, 119(44), 10793–10804. https://doi.org/10.1021/ja970995u
Hinderling, C. et al. (1997) ‘A combined gas-phase, solution-phase, and computational study of C−H activation by cationic iridium(III) complexes’, Journal of the American Chemical Society, 119(44), pp. 10793–10804. Available at: https://doi.org/10.1021/ja970995u.
C. Hinderling, D. Feichtinger, D. A. Plattner, and P. Chen, “A combined gas-phase, solution-phase, and computational study of C−H activation by cationic iridium(III) complexes,” Journal of the American Chemical Society, vol. 119, no. 44, pp. 10793–10804, 1997, doi: 10.1021/ja970995u.
HINDERLING, Christian, Derek FEICHTINGER, Dietmar A. PLATTNER und Peter CHEN, 1997. A combined gas-phase, solution-phase, and computational study of C−H activation by cationic iridium(III) complexes. Journal of the American Chemical Society. 1997. Bd. 119, Nr. 44, S. 10793–10804. DOI 10.1021/ja970995u
Hinderling, Christian, Derek Feichtinger, Dietmar A. Plattner, and Peter Chen. 1997. “A Combined Gas-Phase, Solution-Phase, and Computational Study of C−H Activation by Cationic iridium(III) Complexes.” Journal of the American Chemical Society 119 (44): 10793–804. https://doi.org/10.1021/ja970995u.
Hinderling, Christian, et al. “A Combined Gas-Phase, Solution-Phase, and Computational Study of C−H Activation by Cationic iridium(III) Complexes.” Journal of the American Chemical Society, vol. 119, no. 44, 1997, pp. 10793–804, https://doi.org/10.1021/ja970995u.


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