New phenolic N-methylquinolinium single crystals for second-order nonlinear optics

Kim, Ji-Soo; Lee, Seung-Heon; Jazbinsek, Mojca; Yun, Hoseop; Kim, Jongtaek; Lee, Yoon Sup; Kim, Jun Wan; Rotermund, Fabian; Kwon, O-Pil

doi:10.1016/j.optmat.2015.03.023

Publication type:	Article in scientific journal
Type of review:	Peer review (publication)
Title:	New phenolic N-methylquinolinium single crystals for second-order nonlinear optics
Authors:	Kim, Ji-Soo Lee, Seung-Heon Jazbinsek, Mojca Yun, Hoseop Kim, Jongtaek Lee, Yoon Sup Kim, Jun Wan Rotermund, Fabian Kwon, O-Pil
DOI:	10.1016/j.optmat.2015.03.023
Published in:	Optical Materials
Volume(Issue):	45
Page(s):	136
Pages to:	140
Issue Date:	2015
Publisher / Ed. Institution:	Elsevier
ISSN:	0925-3467
Language:	English
Subjects:	Nonlinear optics; Organic crystals; Quinolinium crystals; Crystal growth; Phenolic crystals
Subject (DDC):	540: Chemistry 621.3: Electrical, communications, control engineering
Abstract:	Highly efficient nonlinear optical quinolinium single crystals are newly designed and synthesized. The quinolinium single crystals consist of a 2-(4-hydroxystyryl)-1-methylquinolinium cation possessing large molecular optical nonlinearity and a 2,4,6-trimethylbenzenesulfonate counter anion. The quinolinium crystals exhibit monoclinic acentric space group P21 symmetry, resulting in large macroscopic nonlinear optical response, which is comparable with those of highly nonlinear optical configurationally locked polyene crystals. Plate-shaped bulk quinolinium crystals with an area of up to 56 mm2 are successfully grown by the solution growth method. Single quinolinium crystals exhibit a large transparency range (550-1600 nm) in the optical region and a relatively low absorption coefficient in the THz region.
URI:	https://digitalcollection.zhaw.ch/handle/11475/10787
Fulltext version:	Published version
License (according to publishing contract):	Licence according to publishing contract
Departement:	School of Engineering
Organisational Unit:	Institute of Computational Physics (ICP)
Appears in collections:	Publikationen School of Engineering

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Kim, J.-S., Lee, S.-H., Jazbinsek, M., Yun, H., Kim, J., Lee, Y. S., Kim, J. W., Rotermund, F., & Kwon, O.-P. (2015). New phenolic N-methylquinolinium single crystals for second-order nonlinear optics. Optical Materials, 45, 136–140. https://doi.org/10.1016/j.optmat.2015.03.023

Kim, J.-S. et al. (2015) ‘New phenolic N-methylquinolinium single crystals for second-order nonlinear optics’, Optical Materials, 45, pp. 136–140. Available at: https://doi.org/10.1016/j.optmat.2015.03.023.

J.-S. Kim et al., “New phenolic N-methylquinolinium single crystals for second-order nonlinear optics,” Optical Materials, vol. 45, pp. 136–140, 2015, doi: 10.1016/j.optmat.2015.03.023.

KIM, Ji-Soo, Seung-Heon LEE, Mojca JAZBINSEK, Hoseop YUN, Jongtaek KIM, Yoon Sup LEE, Jun Wan KIM, Fabian ROTERMUND und O-Pil KWON, 2015. New phenolic N-methylquinolinium single crystals for second-order nonlinear optics. Optical Materials. 2015. Bd. 45, S. 136–140. DOI 10.1016/j.optmat.2015.03.023

Kim, Ji-Soo, Seung-Heon Lee, Mojca Jazbinsek, Hoseop Yun, Jongtaek Kim, Yoon Sup Lee, Jun Wan Kim, Fabian Rotermund, and O-Pil Kwon. 2015. “New Phenolic N-Methylquinolinium Single Crystals for Second-Order Nonlinear Optics.” Optical Materials 45: 136–40. https://doi.org/10.1016/j.optmat.2015.03.023.

Kim, Ji-Soo, et al. “New Phenolic N-Methylquinolinium Single Crystals for Second-Order Nonlinear Optics.” Optical Materials, vol. 45, 2015, pp. 136–40, https://doi.org/10.1016/j.optmat.2015.03.023.