Title: Short, facile, and high-yielding synthesis of extremely efficient pincer-type Suzuki catalysts bearing aminophosphine substituents
Authors : Bolliger, Jeanne L.
Blacque, Olivier
Frech, Christian M.
Published in : Angewandte Chemie : international edition
Volume(Issue) : 46
Issue : 34
Pages : 6514
Pages to: 6517
Publisher / Ed. Institution : Wiley
Issue Date: 2007
License (according to publishing contract) : Licence according to publishing contract
Type of review: Peer review (Publication)
Language : English
Subject (DDC) : 540: Chemistry
Abstract: Feeling the pinch: Aryl bromides can be coupled with phenylboronic acid quantitatively within a few minutes by using pincer‐type catalysts bearing aminophosphine substituents. [Pd(Cl)2P(NR2)3] has been used as a template for the pincer core directly on the metal center (see scheme, NR2=piperidinyl, X=NH or O), which makes the independent synthesis and purification of the air‐ and moisture‐sensitive ligand systems unnecessary.
Departement: Life Sciences and Facility Management
Publication type: Article in scientific Journal
DOI : 10.1002/anie.200701804
ISSN: 1433-7851
URI: https://digitalcollection.zhaw.ch/handle/11475/10511
Appears in Collections:Publikationen Life Sciences und Facility Management

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