| Publikationstyp: | Beitrag in wissenschaftlicher Zeitschrift |
| Art der Begutachtung: | Peer review (Publikation) |
| Titel: | P Csp3 P and P Csp2 P palladium(II) hydride pincer complexes : small structural difference-large effect on reactivity |
| Autor/-in: | Gerber, Roman Fox, Thomas Frech, Christian M. |
| DOI: | 10.1002/chem.201000247 |
| Erschienen in: | Chemistry - A European Journal |
| Band(Heft): | 16 |
| Heft: | 23 |
| Seite(n): | 6771 |
| Seiten bis: | 6775 |
| Erscheinungsdatum: | 2010 |
| Verlag / Hrsg. Institution: | Wiley |
| ISSN: | 0947-6539 1521-3765 |
| Sprache: | Englisch |
| Fachgebiet (DDC): | 540: Chemie |
| Zusammenfassung: | Little and large! The aliphatic palladium(II) pincer hydride complex undergoes smooth dihydrogen evolution and formation of the stable palladium(II) hydroxide complex when an excess of water is added to a solution of the complex in THF. This reactivity is strikingly different when compared to its aromatic analogue and can be attributed to the stronger trans influence of the aliphatic pincer unit. The reaction is reversible and fast hydrogenolysis is observed. |
| URI: | https://digitalcollection.zhaw.ch/handle/11475/10469 |
| Volltext Version: | Publizierte Version |
| Lizenz (gemäss Verlagsvertrag): | Lizenz gemäss Verlagsvertrag |
| Departement: | Life Sciences und Facility Management |
| Enthalten in den Sammlungen: | Publikationen Life Sciences und Facility Management |
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Gerber, R., Fox, T., & Frech, Christian M. (2010). P Csp3 P and P Csp2 P palladium(II) hydride pincer complexes : small structural difference-large effect on reactivity. Chemistry - A European Journal, 16(23), 6771–6775. https://doi.org/10.1002/chem.201000247
Gerber, R., Fox, T. and Frech, Christian M. (2010) ‘P Csp3 P and P Csp2 P palladium(II) hydride pincer complexes : small structural difference-large effect on reactivity’, Chemistry - A European Journal, 16(23), pp. 6771–6775. Available at: https://doi.org/10.1002/chem.201000247.
R. Gerber, T. Fox, and Christian M. Frech, “P Csp3 P and P Csp2 P palladium(II) hydride pincer complexes : small structural difference-large effect on reactivity,” Chemistry - A European Journal, vol. 16, no. 23, pp. 6771–6775, 2010, doi: 10.1002/chem.201000247.
GERBER, Roman, Thomas FOX und Christian M. FRECH, 2010. P Csp3 P and P Csp2 P palladium(II) hydride pincer complexes : small structural difference-large effect on reactivity. Chemistry - A European Journal. 2010. Bd. 16, Nr. 23, S. 6771–6775. DOI 10.1002/chem.201000247
Gerber, Roman, Thomas Fox, and Christian M. Frech. 2010. “P Csp3 P and P Csp2 P palladium(II) Hydride Pincer Complexes : Small Structural Difference-Large Effect on Reactivity.” Chemistry - A European Journal 16 (23): 6771–75. https://doi.org/10.1002/chem.201000247.
Gerber, Roman, et al. “P Csp3 P and P Csp2 P palladium(II) Hydride Pincer Complexes : Small Structural Difference-Large Effect on Reactivity.” Chemistry - A European Journal, vol. 16, no. 23, 2010, pp. 6771–75, https://doi.org/10.1002/chem.201000247.
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