Title: P Csp3 P and P Csp2 P palladium(II) hydride pincer complexes : small structural difference-large effect on reactivity
Authors : Gerber, Roman
Fox, Thomas
Frech, Christian M.
Published in : Chemistry - a European journal
Volume(Issue) : 16
Issue : 23
Pages : 6771
Pages to: 6775
Publisher / Ed. Institution : Wiley
Issue Date: 2010
License (according to publishing contract) : Licence according to publishing contract
Type of review: Peer review (Publication)
Language : English
Subject (DDC) : 540: Chemistry
Abstract: Little and large! The aliphatic palladium(II) pincer hydride complex undergoes smooth dihydrogen evolution and formation of the stable palladium(II) hydroxide complex when an excess of water is added to a solution of the complex in THF. This reactivity is strikingly different when compared to its aromatic analogue and can be attributed to the stronger trans influence of the aliphatic pincer unit. The reaction is reversible and fast hydrogenolysis is observed.
Departement: Life Sciences and Facility Management
Publication type: Article in scientific Journal
DOI : 10.1002/chem.201000247
ISSN: 0947-6539
URI: https://digitalcollection.zhaw.ch/handle/11475/10469
Appears in Collections:Publikationen Life Sciences und Facility Management

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