| Publication type: | Article in scientific journal |
| Type of review: | Peer review (publication) |
| Title: | P Csp3 P and P Csp2 P palladium(II) hydride pincer complexes : small structural difference-large effect on reactivity |
| Authors: | Gerber, Roman Fox, Thomas Frech, Christian M. |
| DOI: | 10.1002/chem.201000247 |
| Published in: | Chemistry - A European Journal |
| Volume(Issue): | 16 |
| Issue: | 23 |
| Page(s): | 6771 |
| Pages to: | 6775 |
| Issue Date: | 2010 |
| Publisher / Ed. Institution: | Wiley |
| ISSN: | 0947-6539 1521-3765 |
| Language: | English |
| Subject (DDC): | 540: Chemistry |
| Abstract: | Little and large! The aliphatic palladium(II) pincer hydride complex undergoes smooth dihydrogen evolution and formation of the stable palladium(II) hydroxide complex when an excess of water is added to a solution of the complex in THF. This reactivity is strikingly different when compared to its aromatic analogue and can be attributed to the stronger trans influence of the aliphatic pincer unit. The reaction is reversible and fast hydrogenolysis is observed. |
| URI: | https://digitalcollection.zhaw.ch/handle/11475/10469 |
| Fulltext version: | Published version |
| License (according to publishing contract): | Licence according to publishing contract |
| Departement: | Life Sciences and Facility Management |
| Appears in collections: | Publikationen Life Sciences und Facility Management |
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Gerber, R., Fox, T., & Frech, Christian M. (2010). P Csp3 P and P Csp2 P palladium(II) hydride pincer complexes : small structural difference-large effect on reactivity. Chemistry - A European Journal, 16(23), 6771–6775. https://doi.org/10.1002/chem.201000247
Gerber, R., Fox, T. and Frech, Christian M. (2010) ‘P Csp3 P and P Csp2 P palladium(II) hydride pincer complexes : small structural difference-large effect on reactivity’, Chemistry - A European Journal, 16(23), pp. 6771–6775. Available at: https://doi.org/10.1002/chem.201000247.
R. Gerber, T. Fox, and Christian M. Frech, “P Csp3 P and P Csp2 P palladium(II) hydride pincer complexes : small structural difference-large effect on reactivity,” Chemistry - A European Journal, vol. 16, no. 23, pp. 6771–6775, 2010, doi: 10.1002/chem.201000247.
GERBER, Roman, Thomas FOX und Christian M. FRECH, 2010. P Csp3 P and P Csp2 P palladium(II) hydride pincer complexes : small structural difference-large effect on reactivity. Chemistry - A European Journal. 2010. Bd. 16, Nr. 23, S. 6771–6775. DOI 10.1002/chem.201000247
Gerber, Roman, Thomas Fox, and Christian M. Frech. 2010. “P Csp3 P and P Csp2 P palladium(II) Hydride Pincer Complexes : Small Structural Difference-Large Effect on Reactivity.” Chemistry - A European Journal 16 (23): 6771–75. https://doi.org/10.1002/chem.201000247.
Gerber, Roman, et al. “P Csp3 P and P Csp2 P palladium(II) Hydride Pincer Complexes : Small Structural Difference-Large Effect on Reactivity.” Chemistry - A European Journal, vol. 16, no. 23, 2010, pp. 6771–75, https://doi.org/10.1002/chem.201000247.
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