|Publication type:||Article in scientific journal|
|Type of review:||Peer review (publication)|
|Title:||P Csp3 P and P Csp2 P palladium(II) hydride pincer complexes : small structural difference-large effect on reactivity|
|Authors :||Gerber, Roman|
Frech, Christian M.
|Published in :||Chemistry - A European Journal|
|Publisher / Ed. Institution :||Wiley|
|Subject (DDC) :||540: Chemistry|
|Abstract:||Little and large! The aliphatic palladium(II) pincer hydride complex undergoes smooth dihydrogen evolution and formation of the stable palladium(II) hydroxide complex when an excess of water is added to a solution of the complex in THF. This reactivity is strikingly different when compared to its aromatic analogue and can be attributed to the stronger trans influence of the aliphatic pincer unit. The reaction is reversible and fast hydrogenolysis is observed.|
|Fulltext version :||Published version|
|License (according to publishing contract) :||Licence according to publishing contract|
|Departement:||Life Sciences and Facility Management|
|Appears in Collections:||Publikationen Life Sciences und Facility Management|
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.