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Please use this identifier to cite or link to this item: https://doi.org/10.21256/zhaw-25297
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dc.contributor.authorTu, Kunkun-
dc.contributor.authorBüchele, Simon-
dc.contributor.authorMitchell, Sharon-
dc.contributor.authorStricker, Laura-
dc.contributor.authorLiu, Chun-
dc.contributor.authorGoldhahn, Christian-
dc.contributor.authorAllaz, Julien-
dc.contributor.authorDing, Yong-
dc.contributor.authorGünther, Roman-
dc.contributor.authorZhang, Zhidong-
dc.contributor.authorSun, Jianguo-
dc.contributor.authorStucki, Sandro-
dc.contributor.authorPanzarasa, Guido-
dc.contributor.authorZeeman, Samuel C-
dc.contributor.authorBurgert, Ingo-
dc.contributor.authorPérez-Ramírez, Javier-
dc.contributor.authorKeplinger, Tobias-
dc.date.accessioned2022-07-14T09:25:33Z-
dc.date.available2022-07-14T09:25:33Z-
dc.date.issued2022-02-16-
dc.identifier.issn1944-8244de_CH
dc.identifier.issn1944-8252de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/25297-
dc.description.abstractThe development of controlled processes for continuous hydrogen generation from solid-state storage chemicals such as ammonia borane is central to integrating renewable hydrogen into a clean energy mix. However, to date, most reported platforms operate in batch mode, posing a challenge for controllable hydrogen release, catalyst reusability, and large-scale operation. To address these issues, we developed flow-through wood-based catalytic microreactors, characterized by inherent natural oriented microchannels. The prepared structured catalysts utilize silver-promoted palladium nanoparticles supported on metal-organic framework (MOF)-coated wood microreactors as the active phase. Catalytic tests demonstrate their highly controllable hydrogen production in continuous mode, and by adjusting the ammonia borane flow and wood species, we reach stable productivities of up to 10.4 cmH23 min-1 cmcat-3. The modular design of the structured catalysts proves readily scalable. Our versatile approach is applicable for other metals and MOF combinations, thus comprising a sustainable and scalable platform for catalytic dehydrogenations and applications in the energy-water nexus.de_CH
dc.language.isoende_CH
dc.publisherAmerican Chemical Societyde_CH
dc.relation.ispartofACS Applied Materials & Interfacesde_CH
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/4.0/de_CH
dc.subjectFlow reactorde_CH
dc.subjectHydrogen generationde_CH
dc.subjectMetal−organic frameworkde_CH
dc.subjectStructured catalystsde_CH
dc.subjectWoodde_CH
dc.subject.ddc540: Chemiede_CH
dc.titleNatural wood-based catalytic membrane microreactors for continuous hydrogen generationde_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementSchool of Engineeringde_CH
zhaw.organisationalunitInstitute of Materials and Process Engineering (IMPE)de_CH
dc.identifier.doi10.1021/acsami.1c22850de_CH
dc.identifier.doi10.21256/zhaw-25297-
dc.identifier.pmid35107245de_CH
zhaw.funding.euNode_CH
zhaw.issue6de_CH
zhaw.originated.zhawYesde_CH
zhaw.pages.end8426de_CH
zhaw.pages.start8417de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume14de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
zhaw.funding.snf184821, 192336de_CH
zhaw.webfeedKlebstoffe und Polymere Materialiende_CH
zhaw.author.additionalNode_CH
zhaw.display.portraitYesde_CH
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Tu, K., Büchele, S., Mitchell, S., Stricker, L., Liu, C., Goldhahn, C., Allaz, J., Ding, Y., Günther, R., Zhang, Z., Sun, J., Stucki, S., Panzarasa, G., Zeeman, S. C., Burgert, I., Pérez-Ramírez, J., & Keplinger, T. (2022). Natural wood-based catalytic membrane microreactors for continuous hydrogen generation. ACS Applied Materials & Interfaces, 14(6), 8417–8426. https://doi.org/10.1021/acsami.1c22850
Tu, K. et al. (2022) ‘Natural wood-based catalytic membrane microreactors for continuous hydrogen generation’, ACS Applied Materials & Interfaces, 14(6), pp. 8417–8426. Available at: https://doi.org/10.1021/acsami.1c22850.
K. Tu et al., “Natural wood-based catalytic membrane microreactors for continuous hydrogen generation,” ACS Applied Materials & Interfaces, vol. 14, no. 6, pp. 8417–8426, Feb. 2022, doi: 10.1021/acsami.1c22850.
TU, Kunkun, Simon BÜCHELE, Sharon MITCHELL, Laura STRICKER, Chun LIU, Christian GOLDHAHN, Julien ALLAZ, Yong DING, Roman GÜNTHER, Zhidong ZHANG, Jianguo SUN, Sandro STUCKI, Guido PANZARASA, Samuel C ZEEMAN, Ingo BURGERT, Javier PÉREZ-RAMÍREZ und Tobias KEPLINGER, 2022. Natural wood-based catalytic membrane microreactors for continuous hydrogen generation. ACS Applied Materials & Interfaces. 16 Februar 2022. Bd. 14, Nr. 6, S. 8417–8426. DOI 10.1021/acsami.1c22850
Tu, Kunkun, Simon Büchele, Sharon Mitchell, Laura Stricker, Chun Liu, Christian Goldhahn, Julien Allaz, et al. 2022. “Natural Wood-Based Catalytic Membrane Microreactors for Continuous Hydrogen Generation.” ACS Applied Materials & Interfaces 14 (6): 8417–26. https://doi.org/10.1021/acsami.1c22850.
Tu, Kunkun, et al. “Natural Wood-Based Catalytic Membrane Microreactors for Continuous Hydrogen Generation.” ACS Applied Materials & Interfaces, vol. 14, no. 6, Feb. 2022, pp. 8417–26, https://doi.org/10.1021/acsami.1c22850.


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