Publikationstyp: | Beitrag in wissenschaftlicher Zeitschrift |
Art der Begutachtung: | Peer review (Publikation) |
Titel: | Polarization of charge-transfer bands and rectification in hexadecylquinolinium 7,7,8-tricyanoquinodimethanide and its tetrafluoro analog |
Autor/-in: | Honciuc, Andrei Otsuka, Akihiro Wang, Yu-Hsiang McElwee, Samuel K. Woski, Stephen A. Saito, Gunzi Metzger, Robert M. |
DOI: | 10.1021/jp056910q |
Erschienen in: | The Journal of Physical Chemistry B |
Band(Heft): | 110 |
Heft: | 31 |
Seite(n): | 15085 |
Seiten bis: | 15093 |
Erscheinungsdatum: | 2006 |
Verlag / Hrsg. Institution: | American Chemical Society |
ISSN: | 1520-6106 1520-5207 |
Sprache: | Englisch |
Schlagwörter: | Electrodes; Gold; Molecular structure; Nitriles; Quinolines; Artificial membranes |
Fachgebiet (DDC): | 540: Chemie |
Zusammenfassung: | A Langmuir-Blodgett (LB) multilayer film of the unimolecular rectifier hexadecyl-gamma-quinolinium-7,7,8-tricyanoquinodimethanide (C(16)H(33)gammaQ-3CNQ) has two distinct polarized charge-transfer bands, one at lower film pressures (28 mN m(-1)) with a peak at 530 nm, due to an intramolecular charge transfer or intervalence transfer (IVT); past the collapse point (32 to 35 mN m(-1)), this band disappears, and a new intermolecular charge-transfer band appears with peak at 570 nm. An LB multilayer film of the tetrafluoro analogue, hexadecyl-gamma-quinolinium-2,3,5,6-tetrafluoro-7,7,8-tricyanoquinodimethanide (C(16)H(33)gammaQ-3CNQF(4)) shows, for all film pressures, only one IVT band with a peak at 504 nm; when sandwiched between gold electrodes, (C(16)H(33)gammaQ-3CNQF(4) is also an LB monolayer electrical rectifier. |
URI: | https://digitalcollection.zhaw.ch/handle/11475/13763 |
Volltext Version: | Publizierte Version |
Lizenz (gemäss Verlagsvertrag): | Lizenz gemäss Verlagsvertrag |
Departement: | Life Sciences und Facility Management |
Enthalten in den Sammlungen: | Publikationen Life Sciences und Facility Management |
Dateien zu dieser Ressource:
Es gibt keine Dateien zu dieser Ressource.
Zur Langanzeige
Honciuc, A., Otsuka, A., Wang, Y.-H., McElwee, S. K., Woski, S. A., Saito, G., & Metzger, R. M. (2006). Polarization of charge-transfer bands and rectification in hexadecylquinolinium 7,7,8-tricyanoquinodimethanide and its tetrafluoro analog. The Journal of Physical Chemistry B, 110(31), 15085–15093. https://doi.org/10.1021/jp056910q
Honciuc, A. et al. (2006) ‘Polarization of charge-transfer bands and rectification in hexadecylquinolinium 7,7,8-tricyanoquinodimethanide and its tetrafluoro analog’, The Journal of Physical Chemistry B, 110(31), pp. 15085–15093. Available at: https://doi.org/10.1021/jp056910q.
A. Honciuc et al., “Polarization of charge-transfer bands and rectification in hexadecylquinolinium 7,7,8-tricyanoquinodimethanide and its tetrafluoro analog,” The Journal of Physical Chemistry B, vol. 110, no. 31, pp. 15085–15093, 2006, doi: 10.1021/jp056910q.
HONCIUC, Andrei, Akihiro OTSUKA, Yu-Hsiang WANG, Samuel K. MCELWEE, Stephen A. WOSKI, Gunzi SAITO und Robert M. METZGER, 2006. Polarization of charge-transfer bands and rectification in hexadecylquinolinium 7,7,8-tricyanoquinodimethanide and its tetrafluoro analog. The Journal of Physical Chemistry B. 2006. Bd. 110, Nr. 31, S. 15085–15093. DOI 10.1021/jp056910q
Honciuc, Andrei, Akihiro Otsuka, Yu-Hsiang Wang, Samuel K. McElwee, Stephen A. Woski, Gunzi Saito, and Robert M. Metzger. 2006. “Polarization of Charge-Transfer Bands and Rectification in Hexadecylquinolinium 7,7,8-Tricyanoquinodimethanide and Its Tetrafluoro Analog.” The Journal of Physical Chemistry B 110 (31): 15085–93. https://doi.org/10.1021/jp056910q.
Honciuc, Andrei, et al. “Polarization of Charge-Transfer Bands and Rectification in Hexadecylquinolinium 7,7,8-Tricyanoquinodimethanide and Its Tetrafluoro Analog.” The Journal of Physical Chemistry B, vol. 110, no. 31, 2006, pp. 15085–93, https://doi.org/10.1021/jp056910q.
Alle Ressourcen in diesem Repository sind urheberrechtlich geschützt, soweit nicht anderweitig angezeigt.