Please use this identifier to cite or link to this item:
https://doi.org/10.21256/zhaw-12532| Publication type: | Article in scientific journal |
| Type of review: | Peer review (publication) |
| Title: | Strategies for localizing multiple functional groups in mesoporous silica particles through a one-pot synthesis |
| Authors: | Zucchetto, Nicola Brühwiler, Dominik |
| DOI: | 10.1021/acs.chemmater.8b03603 10.21256/zhaw-12532 |
| Published in: | Chemistry of Materials |
| Volume(Issue): | 30 |
| Issue: | 20 |
| Page(s): | 7280 |
| Pages to: | 7286 |
| Issue Date: | 2018 |
| Publisher / Ed. Institution: | American Chemical Society |
| ISSN: | 0897-4756 1520-5002 |
| Language: | English |
| Subject (DDC): | 540: Chemistry |
| Abstract: | The process of postcondensation for the functionalization of mesoporous silica is based on the cooperation between the end-on growth of arrays of silica nanochannels and the steric hindrance of the functional silanes (R-silanes). To obtain particles with differently functionalized surfaces (thiol and amino groups), the delayed addition of another R-silane was introduced. This tandem postcondensation approach allows for three selective functionalization strategies, depending on the mobility and the steric hindrance of the R-silanes. Following these one-pot synthesis strategies, functional groups can be placed independently on the pore entrances and on the internal surface of the mesoporous silica particles. Confocal laser scanning microscopy was used to image the functional group distribution after selective coupling with a fluorescent dye. Nitrogen sorption measurements were conducted to confirm the well-defined mesoporosity of the functionalized products. |
| URI: | https://digitalcollection.zhaw.ch/handle/11475/12532 |
| Fulltext version: | Published version |
| License (according to publishing contract): | Licence according to publishing contract |
| Departement: | Life Sciences and Facility Management |
| Organisational Unit: | Institute of Chemistry and Biotechnology (ICBT) |
| Published as part of the ZHAW project: | Multimodal Porous Particles |
| Appears in collections: | Publikationen Life Sciences und Facility Management |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 2018_Zucchetto_Localizing-functional-groups-in-mesoporous-silica-particles.pdf | 3.21 MB | Adobe PDF |  View/Open |
Show full item record
Zucchetto, N., & Brühwiler, D. (2018). Strategies for localizing multiple functional groups in mesoporous silica particles through a one-pot synthesis. Chemistry of Materials, 30(20), 7280–7286. https://doi.org/10.1021/acs.chemmater.8b03603
Zucchetto, N. and Brühwiler, D. (2018) ‘Strategies for localizing multiple functional groups in mesoporous silica particles through a one-pot synthesis’, Chemistry of Materials, 30(20), pp. 7280–7286. Available at: https://doi.org/10.1021/acs.chemmater.8b03603.
N. Zucchetto and D. Brühwiler, “Strategies for localizing multiple functional groups in mesoporous silica particles through a one-pot synthesis,” Chemistry of Materials, vol. 30, no. 20, pp. 7280–7286, 2018, doi: 10.1021/acs.chemmater.8b03603.
ZUCCHETTO, Nicola und Dominik BRÜHWILER, 2018. Strategies for localizing multiple functional groups in mesoporous silica particles through a one-pot synthesis. Chemistry of Materials. 2018. Bd. 30, Nr. 20, S. 7280–7286. DOI 10.1021/acs.chemmater.8b03603
Zucchetto, Nicola, and Dominik Brühwiler. 2018. “Strategies for Localizing Multiple Functional Groups in Mesoporous Silica Particles through a One-Pot Synthesis.” Chemistry of Materials 30 (20): 7280–86. https://doi.org/10.1021/acs.chemmater.8b03603.
Zucchetto, Nicola, and Dominik Brühwiler. “Strategies for Localizing Multiple Functional Groups in Mesoporous Silica Particles through a One-Pot Synthesis.” Chemistry of Materials, vol. 30, no. 20, 2018, pp. 7280–86, https://doi.org/10.1021/acs.chemmater.8b03603.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.