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dc.contributor.authorFrech, C. M.-
dc.contributor.authorBlacque, O.-
dc.contributor.authorSchmalle, H. W.-
dc.contributor.authorBerke, H.-
dc.date.accessioned2018-09-12T14:12:12Z-
dc.date.available2018-09-12T14:12:12Z-
dc.date.issued2006-
dc.identifier.issn0947-6539de_CH
dc.identifier.issn1521-3765de_CH
dc.identifier.urihttps://digitalcollection.zhaw.ch/handle/11475/10491-
dc.description.abstractTreatment of the complexes [Re(NO)2(PR3)2][BAr(F)4] (R = Cy, 1 a; R = iPr, 1 b) with phenyldiazomethane gave the cationic benzylidene species [Re{CH(C6H5)}(NO)2(PR3)2][BAr(F)4] (2 a and 2 b) in good yields. Upon reaction of 2 a and 2 b with acetonitrile, the consecutive formation of [Re(N[triple bond]CCH3)(N[triple bond]CPh)(NO)(OC(CH3)=NH)(PR3)][BAr(F)4] (3 a and 3 b) and [Re(NCCH3)(OC{CH3}NH{C6H5})(NO)(PR3)2][BAr(F)4] (4 a and 4 b) was observed. The proposed reaction sequence involves the coupling of coordinated NO, carbene and acetonitrile molecules to yield the (1Z)-N-[imino(phenyl)methyl]ethanimidate ligand. The coupling of the nitrosyl and the benzylidene is anticipated to occur first, forming an oximate species. The subsequent acetonitrile addition can be envisaged as a heteroene reaction of the oximate and the acetonitrile ligand yielding 3 a and 3 b, which in turn can cyclise and undergo a prototropic shift initiated by an internal attack of the ethaneimidate ligand on the benzonitrile moiety to afford 4 a and 4 b.de_CH
dc.language.isoende_CH
dc.publisherWileyde_CH
dc.relation.ispartofChemistry - A European Journalde_CH
dc.rightsLicence according to publishing contractde_CH
dc.subject.ddc540: Chemiede_CH
dc.titleMetal nitrosyl reactivity : acetonitrile-promoted insertion of an alkylidene into a nitrosyl ligand with fission of the NO bondde_CH
dc.typeBeitrag in wissenschaftlicher Zeitschriftde_CH
dcterms.typeTextde_CH
zhaw.departementLife Sciences und Facility Managementde_CH
dc.identifier.doi10.1002/chem.200600286de_CH
dc.identifier.pmid16705618de_CH
zhaw.funding.euNode_CH
zhaw.issue20de_CH
zhaw.originated.zhawNode_CH
zhaw.pages.end5209de_CH
zhaw.pages.start5199de_CH
zhaw.publication.statuspublishedVersionde_CH
zhaw.volume12de_CH
zhaw.publication.reviewPeer review (Publikation)de_CH
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Frech, C. M., Blacque, O., Schmalle, H. W., & Berke, H. (2006). Metal nitrosyl reactivity : acetonitrile-promoted insertion of an alkylidene into a nitrosyl ligand with fission of the NO bond. Chemistry - A European Journal, 12(20), 5199–5209. https://doi.org/10.1002/chem.200600286
Frech, C.M. et al. (2006) ‘Metal nitrosyl reactivity : acetonitrile-promoted insertion of an alkylidene into a nitrosyl ligand with fission of the NO bond’, Chemistry - A European Journal, 12(20), pp. 5199–5209. Available at: https://doi.org/10.1002/chem.200600286.
C. M. Frech, O. Blacque, H. W. Schmalle, and H. Berke, “Metal nitrosyl reactivity : acetonitrile-promoted insertion of an alkylidene into a nitrosyl ligand with fission of the NO bond,” Chemistry - A European Journal, vol. 12, no. 20, pp. 5199–5209, 2006, doi: 10.1002/chem.200600286.
FRECH, C. M., O. BLACQUE, H. W. SCHMALLE und H. BERKE, 2006. Metal nitrosyl reactivity : acetonitrile-promoted insertion of an alkylidene into a nitrosyl ligand with fission of the NO bond. Chemistry - A European Journal. 2006. Bd. 12, Nr. 20, S. 5199–5209. DOI 10.1002/chem.200600286
Frech, C. M., O. Blacque, H. W. Schmalle, and H. Berke. 2006. “Metal Nitrosyl Reactivity : Acetonitrile-Promoted Insertion of an Alkylidene into a Nitrosyl Ligand with Fission of the NO Bond.” Chemistry - A European Journal 12 (20): 5199–5209. https://doi.org/10.1002/chem.200600286.
Frech, C. M., et al. “Metal Nitrosyl Reactivity : Acetonitrile-Promoted Insertion of an Alkylidene into a Nitrosyl Ligand with Fission of the NO Bond.” Chemistry - A European Journal, vol. 12, no. 20, 2006, pp. 5199–209, https://doi.org/10.1002/chem.200600286.


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