[Pd(Cl)2{P(NC5H10)(C6H11)2}2] - a highly effective and extremely versatile palladium-based Negishi catalyst that efficiently and reliably operates at low catalyst loadings

Bolliger, Jeanne L.; Frech, Christian M.

doi:10.1002/chem.201001201

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DC Field	Value	Language
dc.contributor.author	Bolliger, Jeanne L.	-
dc.contributor.author	Frech, Christian M.	-
dc.date.accessioned	2018-09-12T12:50:34Z	-
dc.date.available	2018-09-12T12:50:34Z	-
dc.date.issued	2010	-
dc.identifier.issn	0947-6539	de_CH
dc.identifier.issn	1521-3765	de_CH
dc.identifier.uri	https://digitalcollection.zhaw.ch/handle/11475/10472	-
dc.description.abstract	[Pd(Cl)(2){P(NC(5)H(10))(C(6)H(11))(2)}(2)] (1) has been prepared in quantitative yield by reacting commercially available [Pd(cod)(Cl)(2)] (cod=cyclooctadiene) with readily prepared 1-(dicyclohexylphosphanyl)piperidine in toluene under N(2) within a few minutes at room temperature. Complex 1 has proved to be an excellent Negishi catalyst, capable of quantitatively coupling a wide variety of electronically activated, non-activated, deactivated, sterically hindered, heterocyclic, and functionalized aryl bromides with various (also heterocyclic) arylzinc reagents, typically within a few minutes at 100°C in the presence of just 0.01 mol% of catalyst. Aryl bromides containing nitro, nitrile, ether, ester, hydroxy, carbonyl, and carboxyl groups, as well as acetals, lactones, amides, anilines, alkenes, carboxylic acids, acetic acids, and pyridines and pyrimidines, have been successfully used as coupling partners. Furthermore, electronic and steric variations are tolerated in both reaction partners. Experimental observations strongly indicate that a molecular mechanism is operative.	de_CH
dc.language.iso	en	de_CH
dc.publisher	Wiley	de_CH
dc.relation.ispartof	Chemistry - A European Journal	de_CH
dc.rights	Licence according to publishing contract	de_CH
dc.subject.ddc	540: Chemie	de_CH
dc.title	[Pd(Cl)2{P(NC5H10)(C6H11)2}2] - a highly effective and extremely versatile palladium-based Negishi catalyst that efficiently and reliably operates at low catalyst loadings	de_CH
dc.type	Beitrag in wissenschaftlicher Zeitschrift	de_CH
dcterms.type	Text	de_CH
zhaw.departement	Life Sciences und Facility Management	de_CH
dc.identifier.doi	10.1002/chem.201001201	de_CH
dc.identifier.pmid	20715208	de_CH
zhaw.funding.eu	No	de_CH
zhaw.issue	36	de_CH
zhaw.originated.zhaw	No	de_CH
zhaw.pages.end	11081	de_CH
zhaw.pages.start	11072	de_CH
zhaw.publication.status	publishedVersion	de_CH
zhaw.volume	16	de_CH
zhaw.publication.review	Peer review (Publikation)	de_CH
Appears in collections:	Publikationen Life Sciences und Facility Management

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Bolliger, J. L., & Frech, C. M. (2010). [Pd(Cl)2{P(NC5H10)(C6H11)2}2] - a highly effective and extremely versatile palladium-based Negishi catalyst that efficiently and reliably operates at low catalyst loadings. Chemistry - A European Journal, 16(36), 11072–11081. https://doi.org/10.1002/chem.201001201

Bolliger, J.L. and Frech, C.M. (2010) ‘[Pd(Cl)2{P(NC5H10)(C6H11)2}2] - a highly effective and extremely versatile palladium-based Negishi catalyst that efficiently and reliably operates at low catalyst loadings’, Chemistry - A European Journal, 16(36), pp. 11072–11081. Available at: https://doi.org/10.1002/chem.201001201.

J. L. Bolliger and C. M. Frech, “[Pd(Cl)2{P(NC5H10)(C6H11)2}2] - a highly effective and extremely versatile palladium-based Negishi catalyst that efficiently and reliably operates at low catalyst loadings,” Chemistry - A European Journal, vol. 16, no. 36, pp. 11072–11081, 2010, doi: 10.1002/chem.201001201.

BOLLIGER, Jeanne L. und Christian M. FRECH, 2010. [Pd(Cl)2{P(NC5H10)(C6H11)2}2] - a highly effective and extremely versatile palladium-based Negishi catalyst that efficiently and reliably operates at low catalyst loadings. Chemistry - A European Journal. 2010. Bd. 16, Nr. 36, S. 11072–11081. DOI 10.1002/chem.201001201

Bolliger, Jeanne L., and Christian M. Frech. 2010. “[Pd(Cl)2{P(NC5H10)(C6H11)2}2] - a Highly Effective and Extremely Versatile Palladium-Based Negishi Catalyst That Efficiently and Reliably Operates at Low Catalyst Loadings.” Chemistry - A European Journal 16 (36): 11072–81. https://doi.org/10.1002/chem.201001201.

Bolliger, Jeanne L., and Christian M. Frech. “[Pd(Cl)2{P(NC5H10)(C6H11)2}2] - a Highly Effective and Extremely Versatile Palladium-Based Negishi Catalyst That Efficiently and Reliably Operates at Low Catalyst Loadings.” Chemistry - A European Journal, vol. 16, no. 36, 2010, pp. 11072–81, https://doi.org/10.1002/chem.201001201.