Hydrolysis of ammonia borane catalyzed by aminophosphine-stabilized precursors of rhodium nanoparticles : ligand effects and solvent-controlled product formation

Fetz, Marco; Gerber, Roman; Blacque, Olivier; Frech, Christian M.

doi:10.1002/chem.201003543

Publication type:	Article in scientific journal
Type of review:	Peer review (publication)
Title:	Hydrolysis of ammonia borane catalyzed by aminophosphine-stabilized precursors of rhodium nanoparticles : ligand effects and solvent-controlled product formation
Authors:	Fetz, Marco Gerber, Roman Blacque, Olivier Frech, Christian M.
DOI:	10.1002/chem.201003543
Published in:	Chemistry - A European Journal
Volume(Issue):	17
Issue:	17
Page(s):	4732
Pages to:	4736
Issue Date:	Mar-2011
Publisher / Ed. Institution:	Wiley
ISSN:	0947-6539 1521-3765
Language:	English
Subject (DDC):	540: Chemistry
Abstract:	Releasing hydrogen: Aminophosphine complexes of rhodium are excellent systems for the hydrolysis of H3N-BH3. The release of H2 in THF/H2O mixtures generates NH3 and B(OH)3 and is based on the sequential catalytic dehydrogenation of H3N-BH3−n(OH)n and hydrolysis of H2N-BH2−n(OH)n (n=0–2).
URI:	https://digitalcollection.zhaw.ch/handle/11475/10465
Fulltext version:	Published version
License (according to publishing contract):	Licence according to publishing contract
Departement:	Life Sciences and Facility Management
Appears in collections:	Publikationen Life Sciences und Facility Management

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Fetz, M., Gerber, R., Blacque, O., & Frech, C. M. (2011). Hydrolysis of ammonia borane catalyzed by aminophosphine-stabilized precursors of rhodium nanoparticles : ligand effects and solvent-controlled product formation. Chemistry - A European Journal, 17(17), 4732–4736. https://doi.org/10.1002/chem.201003543

Fetz, M. et al. (2011) ‘Hydrolysis of ammonia borane catalyzed by aminophosphine-stabilized precursors of rhodium nanoparticles : ligand effects and solvent-controlled product formation’, Chemistry - A European Journal, 17(17), pp. 4732–4736. Available at: https://doi.org/10.1002/chem.201003543.

M. Fetz, R. Gerber, O. Blacque, and C. M. Frech, “Hydrolysis of ammonia borane catalyzed by aminophosphine-stabilized precursors of rhodium nanoparticles : ligand effects and solvent-controlled product formation,” Chemistry - A European Journal, vol. 17, no. 17, pp. 4732–4736, Mar. 2011, doi: 10.1002/chem.201003543.

FETZ, Marco, Roman GERBER, Olivier BLACQUE und Christian M. FRECH, 2011. Hydrolysis of ammonia borane catalyzed by aminophosphine-stabilized precursors of rhodium nanoparticles : ligand effects and solvent-controlled product formation. Chemistry - A European Journal. März 2011. Bd. 17, Nr. 17, S. 4732–4736. DOI 10.1002/chem.201003543

Fetz, Marco, Roman Gerber, Olivier Blacque, and Christian M. Frech. 2011. “Hydrolysis of Ammonia Borane Catalyzed by Aminophosphine-Stabilized Precursors of Rhodium Nanoparticles : Ligand Effects and Solvent-Controlled Product Formation.” Chemistry - A European Journal 17 (17): 4732–36. https://doi.org/10.1002/chem.201003543.

Fetz, Marco, et al. “Hydrolysis of Ammonia Borane Catalyzed by Aminophosphine-Stabilized Precursors of Rhodium Nanoparticles : Ligand Effects and Solvent-Controlled Product Formation.” Chemistry - A European Journal, vol. 17, no. 17, Mar. 2011, pp. 4732–36, https://doi.org/10.1002/chem.201003543.